Abstract

Abstract: Mononuclear complexes (3-XPyH)[SbBr 6 ] (X = Cl (I), Br (II)) are synthesized by the reactions of Sb 2 O 3 , Br 2 , and 3-XPy in HBr. Compound I is characterized by X-ray structure analysis (СIF file CCDC no. 1818602). The crystals of compounds I and II are isostructural. The thermal stability of the synthesized complexes is studied by thermogravimetry.

Original languageEnglish
Pages (from-to)128-132
Number of pages5
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume45
Issue number2
DOIs
Publication statusPublished - 1 Feb 2019

Keywords

  • antimony
  • halide complexes
  • thermogravimetry
  • X-ray structure analysis
  • TRANSITION
  • CRYSTAL-STRUCTURE
  • NONABROMOANTIMONATE(V)
  • HYBRID

Fingerprint

Dive into the research topics of 'Mononuclear Sb(V) Bromide Complexes with 3-Halopyridinium Cations: Synthesis, Structures, and Thermal Stability'. Together they form a unique fingerprint.

Cite this