Mononuclear bromide complexes of Sb(V): crystal structures and thermal behaviour

Sergey A. Adonin, Mikhail A. Bondarenko, Denis G. Samsonenko, Evgeniy Yu Semitut, Maxim N. Sokolov, Vladimir P. Fedin

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Reactions of Sb2O3 dissolved in HBr/Br2 and bromides of pyridinium-derived cations result in mononuclear complexes of Sb(V) – (cation)[SbBr6] (cation = 2-chloropyridinium (1), 2-bromopyridinium (2)). Thermal behaviour of 1 and 2, as well as similar previously reported complexes Et4N [SbBr6] (3) and (N-EtPy)[SbBr6] (4), was studied and discussed.

Original languageEnglish
Pages (from-to)102-106
Number of pages5
JournalJournal of Molecular Structure
Volume1160
DOIs
Publication statusPublished - 15 May 2018

Keywords

  • Antimony
  • Halide complexes
  • Thermogravimetry
  • X-ray diffractometry
  • MOLECULAR-DYNAMICS
  • PHASE-TRANSITIONS
  • BISMUTH COMPLEXES
  • IODIDE
  • SALTS
  • BIDENTATE BASE SYSTEMS
  • OPTICAL BAND-GAP
  • LIGHT-HARVESTING MATERIAL
  • HYBRID
  • VIOLOGEN

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