Mono- and Binuclear Chloride and Bromide Complexes of Bi(III) with Double-Charged Cations Based on Pyridine: Syntheses and Crystal Structures

I. D. Gorokh, S. A. Adonin, D. G. Samsonenko, M. N. Sokolov, V. P. Fedin

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Abstract: The reactions of solutions obtained by the reactions of Bi2O3 with 2 M HCl and HBr with the salts containing bis(pyridyl)alkane cations afford mono- and binuclear halide complexes (Py-(CH2)3-Py)3[Bi2Br9]2 (I), (H3O)(Py-(CH2)4-Py)[BiCl6] ⋅ 3H2O (II), and (H2Bpp)2[Bi2Br10] ⋅ 2H2O (Bpp is 1,3-bis(4-pyridyl)propane) (III). The structures of the synthesized compounds are determined by X-ray diffraction analysis (СIF files CCDC no. 1583338–1583340, respectively).

Original languageEnglish
Pages (from-to)502-506
Number of pages5
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume44
Issue number8
DOIs
Publication statusPublished - 1 Aug 2018

Keywords

  • bismuth
  • bromide complexes
  • chloride complexes
  • crystal structure
  • PHOTOCATALYTIC PROPERTIES
  • STABILITY
  • BISMUTH COMPLEXES
  • ebismuth
  • PHOTOVOLTAIC PERFORMANCE
  • HALOGENIDES
  • PHASE-TRANSITION
  • PEROVSKITE
  • HYBRID

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