Modification of sulfide-based photocatalyst with zinc- and nickel-containing compounds: Correlation between photocatalytic activity and photoelectrochemical parameters

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The photoanodes made of Cd0.3Zn0.7S and FTO were prepared and modified by Ni(OH)2, Zn(OH)2, and NiS as co-catalysts. The amounts of the co-catalysts were the same as those in the most active photocatalysts tested earlier in photocatalytic hydrogen production. The obtained electrodes were studied by X-ray diffraction and photoelectron spectroscopy, scanning and transmission electron microscopy, cyclic voltammetry, and electrochemical impedance spectroscopy. The modification of the photoelectrode surface led to the growth of short-circuit current density, power conversion efficiency and photogenerated charge carriers lifetime, while open-circuit voltage, fill factor, and resistivity fell. The changes in the photocatalytic activity and the photoelectrochemical properties of the tested samples were found to correlate with each other, which indicated the same origin of the studied phenomenon.

Original languageEnglish
Pages (from-to)286-294
Number of pages9
JournalRenewable Energy
Volume151
DOIs
Publication statusPublished - May 2020

Keywords

  • CdZnS
  • NaS/NaSO
  • Photocatalytic hydrogen production
  • Photoelectrochemistry
  • Visible light

Fingerprint

Dive into the research topics of 'Modification of sulfide-based photocatalyst with zinc- and nickel-containing compounds: Correlation between photocatalytic activity and photoelectrochemical parameters'. Together they form a unique fingerprint.

Cite this