Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline

P. A. Topchiyan; D. B. Vasilchenko; S. V. Tkachev; I. A. Baydina; I. V. Korolkov; D. G. Sheven; S. V. Korenev

doi:10.1134/S0022476619040152

Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline

P. A. Topchiyan, D. B. Vasilchenko, S. V. Tkachev, I. A. Baydina, I. V. Korolkov, D. G. Sheven, S. V. Korenev

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Abstract

Interaction of iridium(III) nitro-aqua complexes with 1,10-phenanthroline is studied. Complex anions [Ir(phen)(NO ₂ ) ₄ ] ⁻ and [Ir(phen)(OH)(NO ₂ ) ₃ ] ⁻ are isolated in the solid phase. The complex Na[Ir(phen)(NO ₂ ) ₄ ](phen)(H ₂ O) is structurally characterized for the first time. Crystallographic data: a= 8.0752 (5) Ǻ, b= 11.690 (7) Ǻ, c= 14.012 (7) α, α = 105.55(2)°, β = 91,99(2)°, γ = 103,71(2)° space group P-1, Z = 2, ρ _calc = 1,936 g/cm ³ . The coordination sphere of the iridium atom has a distorted octahedral geometry. The obtained structure contains an island motif consisting of the pairs of complex anions [Ir(phen)(NO ₂ ) ₄ ] ⁻ linked to each other by sodium cations.

Original language	English
Pages (from-to)	640-646
Number of pages	7
Journal	Journal of Structural Chemistry
Volume	60
Issue number	4
DOIs	https://doi.org/10.1134/S0022476619040152
Publication status	Published - 1 Apr 2019

Keywords

aquacomplexes
iridium
mass spectrometry
nitro complexes
NMR
phenanthroline
X-ray diffraction
CRYSTAL-STRUCTURE
RH
CARBONYL-COMPOUNDS

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@article{98786a0c9ed34c0094dd65a8db172b8d,

title = "Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline",

abstract = " Interaction of iridium(III) nitro-aqua complexes with 1,10-phenanthroline is studied. Complex anions [Ir(phen)(NO 2 ) 4 ] − and [Ir(phen)(OH)(NO 2 ) 3 ] − are isolated in the solid phase. The complex Na[Ir(phen)(NO 2 ) 4 ](phen)(H 2 O) is structurally characterized for the first time. Crystallographic data: a= 8.0752 (5) Ǻ, b= 11.690 (7) Ǻ, c= 14.012 (7) α, α = 105.55(2)°, β = 91,99(2)°, γ = 103,71(2)° space group P-1, Z = 2, ρ calc = 1,936 g/cm 3 . The coordination sphere of the iridium atom has a distorted octahedral geometry. The obtained structure contains an island motif consisting of the pairs of complex anions [Ir(phen)(NO 2 ) 4 ] − linked to each other by sodium cations. ",

keywords = "aquacomplexes, iridium, mass spectrometry, nitro complexes, NMR, phenanthroline, X-ray diffraction, CRYSTAL-STRUCTURE, RH, CARBONYL-COMPOUNDS",

author = "Topchiyan, {P. A.} and Vasilchenko, {D. B.} and Tkachev, {S. V.} and Baydina, {I. A.} and Korolkov, {I. V.} and Sheven, {D. G.} and Korenev, {S. V.}",

year = "2019",

month = apr,

day = "1",

doi = "10.1134/S0022476619040152",

language = "English",

volume = "60",

pages = "640--646",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "4",

}

TY - JOUR

T1 - Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline

AU - Topchiyan, P. A.

AU - Vasilchenko, D. B.

AU - Tkachev, S. V.

AU - Baydina, I. A.

AU - Korolkov, I. V.

AU - Sheven, D. G.

AU - Korenev, S. V.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - Interaction of iridium(III) nitro-aqua complexes with 1,10-phenanthroline is studied. Complex anions [Ir(phen)(NO 2 ) 4 ] − and [Ir(phen)(OH)(NO 2 ) 3 ] − are isolated in the solid phase. The complex Na[Ir(phen)(NO 2 ) 4 ](phen)(H 2 O) is structurally characterized for the first time. Crystallographic data: a= 8.0752 (5) Ǻ, b= 11.690 (7) Ǻ, c= 14.012 (7) α, α = 105.55(2)°, β = 91,99(2)°, γ = 103,71(2)° space group P-1, Z = 2, ρ calc = 1,936 g/cm 3 . The coordination sphere of the iridium atom has a distorted octahedral geometry. The obtained structure contains an island motif consisting of the pairs of complex anions [Ir(phen)(NO 2 ) 4 ] − linked to each other by sodium cations.

AB - Interaction of iridium(III) nitro-aqua complexes with 1,10-phenanthroline is studied. Complex anions [Ir(phen)(NO 2 ) 4 ] − and [Ir(phen)(OH)(NO 2 ) 3 ] − are isolated in the solid phase. The complex Na[Ir(phen)(NO 2 ) 4 ](phen)(H 2 O) is structurally characterized for the first time. Crystallographic data: a= 8.0752 (5) Ǻ, b= 11.690 (7) Ǻ, c= 14.012 (7) α, α = 105.55(2)°, β = 91,99(2)°, γ = 103,71(2)° space group P-1, Z = 2, ρ calc = 1,936 g/cm 3 . The coordination sphere of the iridium atom has a distorted octahedral geometry. The obtained structure contains an island motif consisting of the pairs of complex anions [Ir(phen)(NO 2 ) 4 ] − linked to each other by sodium cations.

KW - aquacomplexes

KW - iridium

KW - mass spectrometry

KW - nitro complexes

KW - NMR

KW - phenanthroline

KW - X-ray diffraction

KW - CRYSTAL-STRUCTURE

KW - RH

KW - CARBONYL-COMPOUNDS

UR - http://www.scopus.com/inward/record.url?scp=85065414072&partnerID=8YFLogxK

U2 - 10.1134/S0022476619040152

DO - 10.1134/S0022476619040152

M3 - Article

AN - SCOPUS:85065414072

VL - 60

SP - 640

EP - 646

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

Mixed-Ligand Iridium(III) Nitro Complexes with Phenantroline

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