Methyl Propiolate Cluster Complex (Ph                         
                        4
                                                 P)                         
                        2
                                                 [W                         
                        6
                                                 I                         
                        8
                                                 (C≡C–C(O)OCH                         
                        3
                                                 )                         
                        6
                                                 ]

M. A. Mikhailov; P. A. Abramov; A. D. Mironova; M. R. Gallyamov; D. G. Sheven’; V. V. Pervukhin; M. N. Sokolov

doi:10.1134/S1070328419010081

Methyl Propiolate Cluster Complex (Ph ₄ P) ₂ [W ₆ I ₈ (C≡C–C(O)OCH ₃ ) ₆ ]

M. A. Mikhailov, P. A. Abramov, A. D. Mironova, M. R. Gallyamov, D. G. Sheven’, V. V. Pervukhin, M. N. Sokolov

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Abstract: A new organometallic iodide cluster complex (Bu ₄ N) ₂ [W ₆ I ₈ (C≡C–C(O)OCH ₃ ) ₆ ] (I), analogous to the previously described (Bu ₄ N) ₂ [Mo ₆ I ₈ (C≡C–C(O)OCH ₃ ) ₆ ], was obtained by the reaction of (Bu ₄ N) ₂ [W ₆ I ₁₄ ] with silver methyl propiolate AgC≡C–C(O)OCH ₃ . The crystal structure was established for the tetraphenylphosphonium salt (Ph ₄ P) ₂ [W ₆ I ₈ (C≡C–C(O)OCH ₃ ) ₆ ] (II). According to X-ray diffraction (CIF file CCDC no. 1829205), tungsten atoms in II are coordinated by terminal carbon atoms of methyl propiolate ligands at W–C distances of 2.220(12)–2.268(14) Å. The methyl propiolate complexes were characterized by electrospray mass spectrometry, ¹ H and ¹³ C NMR spectroscopy, elemental analysis, and IR spectroscopy.

Original language	English
Pages (from-to)	56-61
Number of pages	6
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	45
Issue number	1
DOIs	https://doi.org/10.1134/S1070328419010081
Publication status	Published - 1 Jan 2019

Keywords

: clusters
crystal structure
iodides
methyl propiolates
organometallic compounds
tungsten
ENERGY
TRIALKYLPHOSPHINES
COMPOUND
IODIDE CLUSTER
HEXANUCLEAR MOLYBDENUM
LUMINESCENCE
POLYMER
CHEMISTRY
clusters

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10.1134/S1070328419010081

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Mikhailov, M. A., Abramov, P. A., Mironova, A. D., Gallyamov, M. R., Sheven’, D. G., Pervukhin, V. V., & Sokolov, M. N. (2019). Methyl Propiolate Cluster Complex (Ph ₄ P) ₂ [W ₆ I ₈ (C≡C–C(O)OCH ₃ ) ₆ ]. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 45(1), 56-61. https://doi.org/10.1134/S1070328419010081

Mikhailov, M. A. ; Abramov, P. A. ; Mironova, A. D. et al. / Methyl Propiolate Cluster Complex (Ph ₄ P) ₂ [W ₆ I ₈ (C≡C–C(O)OCH ₃ ) ₆ ]. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 ; Vol. 45, No. 1. pp. 56-61.

@article{8a55eb40cb54436a89e3122e8bc1d857,

title = "Methyl Propiolate Cluster Complex (Ph 4 P) 2 [W 6 I 8 (C≡C–C(O)OCH 3 ) 6 ]",

abstract = " Abstract: A new organometallic iodide cluster complex (Bu 4 N) 2 [W 6 I 8 (C≡C–C(O)OCH 3 ) 6 ] (I), analogous to the previously described (Bu 4 N) 2 [Mo 6 I 8 (C≡C–C(O)OCH 3 ) 6 ], was obtained by the reaction of (Bu 4 N) 2 [W 6 I 14 ] with silver methyl propiolate AgC≡C–C(O)OCH 3 . The crystal structure was established for the tetraphenylphosphonium salt (Ph 4 P) 2 [W 6 I 8 (C≡C–C(O)OCH 3 ) 6 ] (II). According to X-ray diffraction (CIF file CCDC no. 1829205), tungsten atoms in II are coordinated by terminal carbon atoms of methyl propiolate ligands at W–C distances of 2.220(12)–2.268(14) {\AA}. The methyl propiolate complexes were characterized by electrospray mass spectrometry, 1 H and 13 C NMR spectroscopy, elemental analysis, and IR spectroscopy. ",

keywords = ": clusters, crystal structure, iodides, methyl propiolates, organometallic compounds, tungsten, ENERGY, TRIALKYLPHOSPHINES, COMPOUND, IODIDE CLUSTER, HEXANUCLEAR MOLYBDENUM, LUMINESCENCE, POLYMER, CHEMISTRY, clusters",

author = "Mikhailov, {M. A.} and Abramov, {P. A.} and Mironova, {A. D.} and Gallyamov, {M. R.} and Sheven{\textquoteright}, {D. G.} and Pervukhin, {V. V.} and Sokolov, {M. N.}",

year = "2019",

month = jan,

day = "1",

doi = "10.1134/S1070328419010081",

language = "English",

volume = "45",

pages = "56--61",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "1",

}

Mikhailov, MA, Abramov, PA, Mironova, AD, Gallyamov, MR, Sheven’, DG, Pervukhin, VV & Sokolov, MN 2019, 'Methyl Propiolate Cluster Complex (Ph ₄ P) ₂ [W ₆ I ₈ (C≡C–C(O)OCH ₃ ) ₆ ]', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 1, pp. 56-61. https://doi.org/10.1134/S1070328419010081

Methyl Propiolate Cluster Complex (Ph ₄ P) ₂ [W ₆ I ₈ (C≡C–C(O)OCH ₃ ) ₆ ]. / Mikhailov, M. A.; Abramov, P. A.; Mironova, A. D. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 45, No. 1, 01.01.2019, p. 56-61.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Methyl Propiolate Cluster Complex (Ph 4 P) 2 [W 6 I 8 (C≡C–C(O)OCH 3 ) 6 ]

AU - Mikhailov, M. A.

AU - Abramov, P. A.

AU - Mironova, A. D.

AU - Gallyamov, M. R.

AU - Sheven’, D. G.

AU - Pervukhin, V. V.

AU - Sokolov, M. N.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Abstract: A new organometallic iodide cluster complex (Bu 4 N) 2 [W 6 I 8 (C≡C–C(O)OCH 3 ) 6 ] (I), analogous to the previously described (Bu 4 N) 2 [Mo 6 I 8 (C≡C–C(O)OCH 3 ) 6 ], was obtained by the reaction of (Bu 4 N) 2 [W 6 I 14 ] with silver methyl propiolate AgC≡C–C(O)OCH 3 . The crystal structure was established for the tetraphenylphosphonium salt (Ph 4 P) 2 [W 6 I 8 (C≡C–C(O)OCH 3 ) 6 ] (II). According to X-ray diffraction (CIF file CCDC no. 1829205), tungsten atoms in II are coordinated by terminal carbon atoms of methyl propiolate ligands at W–C distances of 2.220(12)–2.268(14) Å. The methyl propiolate complexes were characterized by electrospray mass spectrometry, 1 H and 13 C NMR spectroscopy, elemental analysis, and IR spectroscopy.

AB - Abstract: A new organometallic iodide cluster complex (Bu 4 N) 2 [W 6 I 8 (C≡C–C(O)OCH 3 ) 6 ] (I), analogous to the previously described (Bu 4 N) 2 [Mo 6 I 8 (C≡C–C(O)OCH 3 ) 6 ], was obtained by the reaction of (Bu 4 N) 2 [W 6 I 14 ] with silver methyl propiolate AgC≡C–C(O)OCH 3 . The crystal structure was established for the tetraphenylphosphonium salt (Ph 4 P) 2 [W 6 I 8 (C≡C–C(O)OCH 3 ) 6 ] (II). According to X-ray diffraction (CIF file CCDC no. 1829205), tungsten atoms in II are coordinated by terminal carbon atoms of methyl propiolate ligands at W–C distances of 2.220(12)–2.268(14) Å. The methyl propiolate complexes were characterized by electrospray mass spectrometry, 1 H and 13 C NMR spectroscopy, elemental analysis, and IR spectroscopy.

KW - : clusters

KW - crystal structure

KW - iodides

KW - methyl propiolates

KW - organometallic compounds

KW - tungsten

KW - ENERGY

KW - TRIALKYLPHOSPHINES

KW - COMPOUND

KW - IODIDE CLUSTER

KW - HEXANUCLEAR MOLYBDENUM

KW - LUMINESCENCE

KW - POLYMER

KW - CHEMISTRY

KW - clusters

UR - http://www.scopus.com/inward/record.url?scp=85064571214&partnerID=8YFLogxK

U2 - 10.1134/S1070328419010081

DO - 10.1134/S1070328419010081

M3 - Article

AN - SCOPUS:85064571214

VL - 45

SP - 56

EP - 61

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 1

ER -

Mikhailov MA, Abramov PA, Mironova AD, Gallyamov MR, Sheven’ DG, Pervukhin VV et al. Methyl Propiolate Cluster Complex (Ph ₄ P) ₂ [W ₆ I ₈ (C≡C–C(O)OCH ₃ ) ₆ ]. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 Jan 1;45(1):56-61. https://doi.org/10.1134/S1070328419010081

Methyl Propiolate Cluster Complex (Ph ₄ P) ₂ [W ₆ I ₈ (C≡C–C(O)OCH ₃ ) ₆ ]

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Keywords

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