Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands

Yu A. Yudina; A. M. Samsonova; V. A. Bolotov; P. A. Demakov; D. G. Samsonenko; V. P. Fedin; D. N. Dybtsev

doi:10.1134/S0022476621100152

Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands

Yu A. Yudina, A. M. Samsonova, V. A. Bolotov, P. A. Demakov, D. G. Samsonenko, V. P. Fedin, D. N. Dybtsev

Department of Natural Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

Three novel metal-organic coordination polymers based on sulfur-containing thieno[3,2-b]thiophene-2,5-dicarboxylic (trans-H₂ttdc) and thieno[2,3-b]thiophene-2,5-dicarboxylic (cis-H₂ttdc) acids are obtained: [Ce₂(DMF)₄(trans-ttdc)₃]·2DMF (1), [Dy₂(DMF)₄(trans-ttdc)₃]·4DMF (2), and [Tb₂(DMF)₄(cis-ttdc)₃]·2.5DMF (3). Structures of the products are determined by single crystal X-ray diffraction. The compositions and nature of compounds 2 and 3 are confirmed by IR spectroscopy, elemental and thermogravimetric analyses. All three compounds are based on binuclear {Ln₂(DMF)₄(RCOO)₆} units organized into 3D frameworks with primitive cubic topology pcu by linear organic linkers. The specific void volume in the structures of 1-3 ranges from 29% to 37%.

Translated title of the contribution	Металл-органические координационные полимеры лантаноидов(III) с тиенотиофендикарбоксилатными лигандами
Original language	English
Pages (from-to)	1599-1606
Number of pages	8
Journal	Journal of Structural Chemistry
Volume	62
Issue number	10
DOIs	https://doi.org/10.1134/S0022476621100152
Publication status	Published - Oct 2021

Keywords

carboxylates
lanthanides
metal-organic coordination polymers
sulfur-containing heterocycles
thiophene
X-ray crystallographic analysis

OECD FOS+WOS

2.05 MATERIALS ENGINEERING
1.04 CHEMICAL SCIENCES

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10.1134/S0022476621100152

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@article{bef4c866ede444c8b5e1deb4b2ae5bfd,

title = "Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands",

abstract = "Three novel metal-organic coordination polymers based on sulfur-containing thieno[3,2-b]thiophene-2,5-dicarboxylic (trans-H2ttdc) and thieno[2,3-b]thiophene-2,5-dicarboxylic (cis-H2ttdc) acids are obtained: [Ce2(DMF)4(trans-ttdc)3]·2DMF (1), [Dy2(DMF)4(trans-ttdc)3]·4DMF (2), and [Tb2(DMF)4(cis-ttdc)3]·2.5DMF (3). Structures of the products are determined by single crystal X-ray diffraction. The compositions and nature of compounds 2 and 3 are confirmed by IR spectroscopy, elemental and thermogravimetric analyses. All three compounds are based on binuclear {Ln2(DMF)4(RCOO)6} units organized into 3D frameworks with primitive cubic topology pcu by linear organic linkers. The specific void volume in the structures of 1-3 ranges from 29% to 37%.",

keywords = "carboxylates, lanthanides, metal-organic coordination polymers, sulfur-containing heterocycles, thiophene, X-ray crystallographic analysis",

author = "Yudina, {Yu A.} and Samsonova, {A. M.} and Bolotov, {V. A.} and Demakov, {P. A.} and Samsonenko, {D. G.} and Fedin, {V. P.} and Dybtsev, {D. N.}",

note = "Funding Information: The work was also supported by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700321-3). Funding Information: The work was supported by the Russian Science Foundation (project No. 18-13-00203). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

year = "2021",

month = oct,

doi = "10.1134/S0022476621100152",

language = "English",

volume = "62",

pages = "1599--1606",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "10",

}

TY - JOUR

T1 - Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands

AU - Yudina, Yu A.

AU - Samsonova, A. M.

AU - Bolotov, V. A.

AU - Demakov, P. A.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

AU - Dybtsev, D. N.

N1 - Funding Information: The work was also supported by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700321-3). Funding Information: The work was supported by the Russian Science Foundation (project No. 18-13-00203). Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/10

Y1 - 2021/10

N2 - Three novel metal-organic coordination polymers based on sulfur-containing thieno[3,2-b]thiophene-2,5-dicarboxylic (trans-H2ttdc) and thieno[2,3-b]thiophene-2,5-dicarboxylic (cis-H2ttdc) acids are obtained: [Ce2(DMF)4(trans-ttdc)3]·2DMF (1), [Dy2(DMF)4(trans-ttdc)3]·4DMF (2), and [Tb2(DMF)4(cis-ttdc)3]·2.5DMF (3). Structures of the products are determined by single crystal X-ray diffraction. The compositions and nature of compounds 2 and 3 are confirmed by IR spectroscopy, elemental and thermogravimetric analyses. All three compounds are based on binuclear {Ln2(DMF)4(RCOO)6} units organized into 3D frameworks with primitive cubic topology pcu by linear organic linkers. The specific void volume in the structures of 1-3 ranges from 29% to 37%.

AB - Three novel metal-organic coordination polymers based on sulfur-containing thieno[3,2-b]thiophene-2,5-dicarboxylic (trans-H2ttdc) and thieno[2,3-b]thiophene-2,5-dicarboxylic (cis-H2ttdc) acids are obtained: [Ce2(DMF)4(trans-ttdc)3]·2DMF (1), [Dy2(DMF)4(trans-ttdc)3]·4DMF (2), and [Tb2(DMF)4(cis-ttdc)3]·2.5DMF (3). Structures of the products are determined by single crystal X-ray diffraction. The compositions and nature of compounds 2 and 3 are confirmed by IR spectroscopy, elemental and thermogravimetric analyses. All three compounds are based on binuclear {Ln2(DMF)4(RCOO)6} units organized into 3D frameworks with primitive cubic topology pcu by linear organic linkers. The specific void volume in the structures of 1-3 ranges from 29% to 37%.

KW - carboxylates

KW - lanthanides

KW - metal-organic coordination polymers

KW - sulfur-containing heterocycles

KW - thiophene

KW - X-ray crystallographic analysis

UR - http://www.scopus.com/inward/record.url?scp=85119130156&partnerID=8YFLogxK

U2 - 10.1134/S0022476621100152

DO - 10.1134/S0022476621100152

M3 - Article

AN - SCOPUS:85119130156

VL - 62

SP - 1599

EP - 1606

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 10

ER -

Metal-organic coordination polymers of lanthanides(III) with thienothiophendicarboxylate ligands

Abstract

Keywords

OECD FOS+WOS

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