Metal-metal bond excitation in colloidal solution of NbS3

Sofya B. Artemkina; Ekaterina D. Grayfer; Mariia N. Kozlova; Svetlana G. Kozlova; Maxim R. Ryzhikov; Igor R. Shein; Vladimir E. Fedorov

doi:10.1016/j.saa.2017.02.005

Metal-metal bond excitation in colloidal solution of NbS₃

Sofya B. Artemkina, Ekaterina D. Grayfer, Mariia N. Kozlova, Svetlana G. Kozlova, Maxim R. Ryzhikov, Igor R. Shein, Vladimir E. Fedorov

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

For the first time the comparison of the theoretical and experimental data have shown that UV–vis absorption in the region of 600 nm in colloidal solution of NbS₃ can be described by the d-d electronic transitions to the antibonding molecular orbital. It is proved that the process leads to excitation of metal-metal bond.

Original language	English
Pages (from-to)	46-50
Number of pages	5
Journal	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume	179
DOIs	https://doi.org/10.1016/j.saa.2017.02.005
Publication status	Published - 15 May 2017

Keywords

Band calculations
DFT
NbS colloidal dispersion
UV–vis spectra
GRAPHENE OXIDE
UV-vis spectra
NIOBIUM TRISULFIDE
OPTICAL-PROPERTIES
GENERALIZED GRADIENT APPROXIMATION
LAYERS
TRANSITION
DIMENSIONAL CONDUCTOR NBS3
NbS3 colloidal dispersion
ELECTRONIC-STRUCTURE

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10.1016/j.saa.2017.02.005

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@article{b0b1ef7417d8427dbf2c3a94334173ee,

title = "Metal-metal bond excitation in colloidal solution of NbS3",

abstract = "For the first time the comparison of the theoretical and experimental data have shown that UV–vis absorption in the region of 600 nm in colloidal solution of NbS3 can be described by the d-d electronic transitions to the antibonding molecular orbital. It is proved that the process leads to excitation of metal-metal bond.",

keywords = "Band calculations, DFT, NbS colloidal dispersion, UV–vis spectra, GRAPHENE OXIDE, UV-vis spectra, NIOBIUM TRISULFIDE, OPTICAL-PROPERTIES, GENERALIZED GRADIENT APPROXIMATION, LAYERS, TRANSITION, DIMENSIONAL CONDUCTOR NBS3, NbS3 colloidal dispersion, ELECTRONIC-STRUCTURE",

author = "Artemkina, {Sofya B.} and Grayfer, {Ekaterina D.} and Kozlova, {Mariia N.} and Kozlova, {Svetlana G.} and Ryzhikov, {Maxim R.} and Shein, {Igor R.} and Fedorov, {Vladimir E.}",

year = "2017",

month = may,

day = "15",

doi = "10.1016/j.saa.2017.02.005",

language = "English",

volume = "179",

pages = "46--50",

journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",

issn = "1386-1425",

publisher = "Elsevier",

}

Metal-metal bond excitation in colloidal solution of NbS₃. / Artemkina, Sofya B.; Grayfer, Ekaterina D.; Kozlova, Mariia N.; Kozlova, Svetlana G.; Ryzhikov, Maxim R.; Shein, Igor R.; Fedorov, Vladimir E.

In: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Vol. 179, 15.05.2017, p. 46-50.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Metal-metal bond excitation in colloidal solution of NbS3

AU - Artemkina, Sofya B.

AU - Grayfer, Ekaterina D.

AU - Kozlova, Mariia N.

AU - Kozlova, Svetlana G.

AU - Ryzhikov, Maxim R.

AU - Shein, Igor R.

AU - Fedorov, Vladimir E.

PY - 2017/5/15

Y1 - 2017/5/15

N2 - For the first time the comparison of the theoretical and experimental data have shown that UV–vis absorption in the region of 600 nm in colloidal solution of NbS3 can be described by the d-d electronic transitions to the antibonding molecular orbital. It is proved that the process leads to excitation of metal-metal bond.

AB - For the first time the comparison of the theoretical and experimental data have shown that UV–vis absorption in the region of 600 nm in colloidal solution of NbS3 can be described by the d-d electronic transitions to the antibonding molecular orbital. It is proved that the process leads to excitation of metal-metal bond.

KW - Band calculations

KW - DFT

KW - NbS colloidal dispersion

KW - UV–vis spectra

KW - GRAPHENE OXIDE

KW - UV-vis spectra

KW - NIOBIUM TRISULFIDE

KW - OPTICAL-PROPERTIES

KW - GENERALIZED GRADIENT APPROXIMATION

KW - LAYERS

KW - TRANSITION

KW - DIMENSIONAL CONDUCTOR NBS3

KW - NbS3 colloidal dispersion

KW - ELECTRONIC-STRUCTURE

UR - http://www.scopus.com/inward/record.url?scp=85013071197&partnerID=8YFLogxK

U2 - 10.1016/j.saa.2017.02.005

DO - 10.1016/j.saa.2017.02.005

M3 - Article

C2 - 28214428

AN - SCOPUS:85013071197

VL - 179

SP - 46

EP - 50

JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

SN - 1386-1425

ER -

Metal-metal bond excitation in colloidal solution of NbS₃

Abstract

Keywords

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