Lithium carboxylate coordination polymers based on trimesic acid

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3 Citations (Scopus)

Abstract

Three new metal-organic coordination polymers (H2NMe2)2[Li3(btc)(Hbtc)(DMF)4] (1), [Li5(DMF)6(btc)(Hbtc)]·2DMF (2), and [Li6(DMF)8(bdc)(Hbtc)] (3) (H3btc is trimesic acid, H2bdc is terephthalic acid) are prepared by heating LiOH with different aromatic carboxylic acids in dimethyl formamide (or its mixture with water). The crystal structures and composition of the compounds are determined by single crystal X-ray diffraction. Compound 1 has a layered structure; compounds 2 and 3 have a framework structure.

Original languageEnglish
Pages (from-to)1048-1055
Number of pages8
JournalJournal of Structural Chemistry
Volume58
Issue number5
DOIs
Publication statusPublished - 1 Sep 2017

Keywords

  • coordination polymers
  • framework structures
  • lithium(I) complexes
  • single crystal X-ray diffraction analysis
  • METAL-ORGANIC FRAMEWORKS

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