Layered metal-organic coordination polymers based on Bi- and trinuclear cadmium blocks and octafluorobiphenyl-4,4′-dicarboxylate anions

A. M. Cheplakova, V. S. Gusarov, D. G. Samsonenko, A. S. Vinogradov, K. A. Kovalenko, M. I. Rakhmanova, V. P. Fedin

Research output: Contribution to journalArticlepeer-review

Abstract

Two new layered metal-organic coordination polymers [Cd2(CH3CN)4(oFBPDC)2]·4CH3CN (1) and [Cd3((CH3)3СOH)4(oFBPDC)3]·3(CH3)3СOH·H2O (2), containing an octafluorobiphenyl-4,4′-dicarboxylic acid anion (oFBPDC2–) are obtained and characterized by the single crystal X-ray diffraction analysis. It is shown that on the long-term storage of 1 in air it transforms into another crystalline phase 1a. Solid 1a exhibits ultraviolet/blue photoluminescence caused by intraligand transitions.

Translated title of the contributionСлоистые металл-органические координационные полимеры на основе бии трехъядерных кадмиевых блоков и октафторбифенил-4,4'-дикарбоксилат-анионов
Original languageEnglish
Pages (from-to)895-904
Number of pages10
JournalJournal of Structural Chemistry
Volume63
Issue number6
DOIs
Publication statusPublished - Jun 2022

Keywords

  • cadmium
  • crystal structure
  • metal-organic coordination polymers
  • octafluorobiphenyl-4,4′-dicarboxylate

OECD FOS+WOS

  • 2.05 MATERIALS ENGINEERING
  • 1.04 CHEMICAL SCIENCES

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