Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2

V. S. Korenev; P. A. Abramov; N. B. Kompankov; A. L. Gushchin; D. G. Sheven; M. N. Sokolov

doi:10.1016/j.jorganchem.2018.01.021

Labile η⁶-areneruthenium sulfide clusters. Crystal structure of [(C₆H₆)₄Ru₅S₄](PF₆)₂ and [(C₆H₆)₄Ru₄S₅](PF₆)₂

V. S. Korenev, P. A. Abramov, N. B. Kompankov, A. L. Gushchin, D. G. Sheven, M. N. Sokolov

Research output: Contribution to journal › Article › peer-review

Abstract

A new labile areneruthenium sulfide complex, [(C₆H₆)₃Ru₃S₂](PF₆)₂ (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C₆H₆)₄Ru₅S₄](PF₆)₂·2CH₃CN (2) and [(C₆H₆)₄Ru₄S₅](PF₆)₂·1.25CH₃CN·0.5H₂O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C₆H₆)₃Ru₃S₂](PF₆)₂ and [Ru₅S₄(C₆H₆)₄](PF₆)₂·2CH₃CN was studied by cyclic voltammetry and reveals one reversible reduction wave.

Original language	English
Pages (from-to)	347-352
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	867
DOIs	https://doi.org/10.1016/j.jorganchem.2018.01.021
Publication status	Published - 15 Jul 2018

Keywords

Areneruthenium complexes
Electrochemistry
Photoactivation
Sulfide clusters
ELECTROCHEMISTRY
RU
TRANSFER HYDROGENATION
POLYMERIZATION
KETONES
LIGANDS
ARENE RUTHENIUM COMPLEXES
ASYMMETRIC EPOXIDATION
CYTOTOXICITY
CATALYSTS

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@article{0ff3378b36244af2b135e93608e62153,

title = "Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2",

abstract = "A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave.",

keywords = "Areneruthenium complexes, Electrochemistry, Photoactivation, Sulfide clusters, ELECTROCHEMISTRY, RU, TRANSFER HYDROGENATION, POLYMERIZATION, KETONES, LIGANDS, ARENE RUTHENIUM COMPLEXES, ASYMMETRIC EPOXIDATION, CYTOTOXICITY, CATALYSTS",

author = "Korenev, {V. S.} and Abramov, {P. A.} and Kompankov, {N. B.} and Gushchin, {A. L.} and Sheven, {D. G.} and Sokolov, {M. N.}",

year = "2018",

month = jul,

day = "15",

doi = "10.1016/j.jorganchem.2018.01.021",

language = "English",

volume = "867",

pages = "347--352",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2

AU - Korenev, V. S.

AU - Abramov, P. A.

AU - Kompankov, N. B.

AU - Gushchin, A. L.

AU - Sheven, D. G.

AU - Sokolov, M. N.

PY - 2018/7/15

Y1 - 2018/7/15

N2 - A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave.

AB - A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave.

KW - Areneruthenium complexes

KW - Electrochemistry

KW - Photoactivation

KW - Sulfide clusters

KW - ELECTROCHEMISTRY

KW - RU

KW - TRANSFER HYDROGENATION

KW - POLYMERIZATION

KW - KETONES

KW - LIGANDS

KW - ARENE RUTHENIUM COMPLEXES

KW - ASYMMETRIC EPOXIDATION

KW - CYTOTOXICITY

KW - CATALYSTS

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U2 - 10.1016/j.jorganchem.2018.01.021

DO - 10.1016/j.jorganchem.2018.01.021

M3 - Article

AN - SCOPUS:85041352611

VL - 867

SP - 347

EP - 352

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

ER -