L-Methioninium picrate

V. V. Ghazaryan, B. A. Zakharov, E. V. Boldyreva, A. M. Petrosyan

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Single crystals of l-methioninium picrate were obtained by evaporation of aqueous solution containing equimolar quantities of each component. l-Methioninium picrate crystallizes in the monoclinic system (space group P21, Z = 2). The asymmetric unit contains one l-methioninium cation and one picrate anion. The carboxyl group of the cation forms an O-H⋯O hydrogen bond with the phenoxy oxygen atom and has an O⋯O distance of 2.669(3) Å. The protonated amino group of the l-methioninium cation forms N-H⋯O hydrogen bonds with the phenoxy oxygen atom of the picrate anion and the carbonyl oxygen atom of the symmetry related cation. The infrared and Raman spectra are recorded and discussed.

Original languageEnglish
Pages (from-to)344-349
Number of pages6
JournalSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume142
DOIs
Publication statusPublished - 15 May 2015

Keywords

  • Crystal structure
  • l-Methioninium picrate
  • NLO crystals
  • Vibrational spectra

Fingerprint Dive into the research topics of 'L-Methioninium picrate'. Together they form a unique fingerprint.

Cite this