IR Microscopy as a Method for Studying the Influence of An External Electric Field on the Spin Crossover Exemplified by the Fe(II) Complex with 2,6-Bis(pyrazol-1-yl)pyridine

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Abstract

The influence of the electric field on the spin state of the single crystal of [Fe(1-Bpp)2][BF4]2 demonstrating the spin crossover phenomenon is studied. The spin state of the complex is determined by the indirect method: FT-IR microscopy. The experimental results show that the application of the external electrostatic field with an intensity of 13 kV/cm exerts no effect on the temperature of the magnetostructural transition of the compound within 0.2 K.

Original languageEnglish
Pages (from-to)326-329
Number of pages4
JournalRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume46
Issue number5
DOIs
Publication statusPublished - 1 May 2020

Keywords

  • coordination compounds
  • FT-IR microscopy
  • iron(II)
  • spin crossover

OECD FOS+WOS

  • 1.04 CHEMICAL SCIENCES

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