In situ X-ray spectroscopic investigation of thermal decomposition of double complex salt [Pt(NH3)4][OsCl6]

T. I. Asanova, I. P. Asanov, M. G. Kim, S. V. Korenev

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

In the paper results of the investigation of the thermal decomposition process of double complex salt [Pt(NH3)4][OsCl6] by x-ray absorption (XAFS) and photoelectron (XPS) spectroscopies have been presented. The data obtained allows a mechanism of the thermal decomposition to be refined. An influence of size effect and nanoalloy formation on chemical shift of Pt and Os is discussed.

Original languageEnglish
Pages (from-to)901-910
Number of pages10
JournalJournal of Structural Chemistry
Volume58
Issue number5
DOIs
Publication statusPublished - 1 Sep 2017

Keywords

  • bimetallic nanoparticles
  • mechanism of thermal decomposition
  • PtOs nanoalloy
  • size effect
  • XAFS
  • XPS
  • [Pt(NH)][OsCl]

Fingerprint Dive into the research topics of 'In situ X-ray spectroscopic investigation of thermal decomposition of double complex salt [Pt(NH<sub>3</sub>)<sub>4</sub>][OsCl<sub>6</sub>]'. Together they form a unique fingerprint.

Cite this