Hysteretic spin crossover in isomeric iron(II) complexes

Mark B. Bushuev, Viktor P. Krivopalov, Elena B. Nikolaenkova, Katerina A. Vinogradova, Yuri V. Gatilov

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Two mononuclear iron(ii) complexes with isomeric N,N,N-tridentate pyrimidine-based ligands were synthesized. Both complexes show reproducible hysteretic spin crossover. Low spin state to high spin state switching is cooperative due to autocatalysis.

Original languageEnglish
Pages (from-to)9585-9591
Number of pages7
JournalDalton Transactions
Volume47
Issue number29
DOIs
Publication statusPublished - 24 Jul 2018

Keywords

  • WIDE THERMAL HYSTERESIS
  • TOMPKINS RATE-EQUATION
  • MAGNETIC-PROPERTIES
  • CRYSTAL-STRUCTURES
  • ROOM-TEMPERATURE
  • TRANSITION
  • STATE
  • KINETICS
  • HEXAFLUOROPHOSPHATE
  • DECOMPOSITION

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