Hydroxylated phosphines as ligands for chalcogenide clusters: Self assembly, transformations and stabilization

Maxim N. Sokolov, Alexander V. Anyushin, Rita Hernandez-Molina, Rosa Llusar, Manuel G. Basallote

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono-and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P-(CH2)x-OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.

Original languageEnglish
Pages (from-to)379-392
Number of pages14
JournalPure and Applied Chemistry
Volume89
Issue number3
DOIs
Publication statusPublished - 1 Mar 2017

Keywords

  • diphosphene
  • ICPC-21
  • low coordination
  • steric protection

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