Highly Proton-Conductive Zinc Metal-Organic Framework Based On Nickel(II) Porphyrinylphosphonate

Yulia Y. Enakieva, Anna A. Sinelshchikova, Mikhail S. Grigoriev, Vladimir V. Chernyshev, Konstantin A. Kovalenko, Irina A. Stenina, Andrey B. Yaroslavtsev, Yulia G. Gorbunova, Aslan Y. Tsivadze

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

The design of new solid-state proton-conducting materials is a great challenge for chemistry and materials science. Herein, a new anionic porphyrinylphosphonate-based MOF (IPCE-1Ni), which involves dimethylammonium (DMA) cations for charge compensation, is reported. As a result of its unique structure, IPCE-1Ni exhibits one of the highest value of the proton conductivity among reported proton-conducting MOF materials based on porphyrins (1.55×10−3 S cm−1 at 75 °C and 80 % relative humidity).

Original languageEnglish
Pages (from-to)10552-10556
Number of pages5
JournalChemistry - A European Journal
Volume25
Issue number45
DOIs
Publication statusPublished - 1 Jul 2019

Keywords

  • conducting materials
  • metal-organic frameworks
  • porous materials
  • porphyrinylphosphonates
  • proton conductivity
  • ACID
  • PHOSPHONATES
  • LUMINESCENT
  • SUPERPROTONIC CONDUCTIVITY
  • CRYSTALLINE
  • TOOL

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