Highly dispersed Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl wire mesh catalyst for autothermal n-hexadecane reforming

T. B. Shoynkhorova, V. N. Rogozhnikov, P. A. Simonov, P. V. Snytnikov, A. N. Salanov, A. V. Kulikov, E. Y. Gerasimov, V. D. Belyaev, D. I. Potemkin, V. A. Sobyanin

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20 Citations (Scopus)

Abstract

Highly dispersed Rh particles supported on Ce0.75Zr0.25O2-δ mixed with alumina were prepared by sorption-hydrolytic deposition technique. Produced catalyst exhibited high activity in autothermal reforming of n-hexadecane, but suffered from coking. Structured Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl catalyst was prepared by strongly bound catalytic coating deposition onto metallic wire mesh to provide effective heat transfer and avoid coking. Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl showed excellent performance in n-hexadecane autothermal reforming providing 100% conversion and stable operation for at least 12 h on stream without detection of any carbon deposits.

Original languageEnglish
Pages (from-to)290-292
Number of pages3
JournalMaterials Letters
Volume214
DOIs
Publication statusPublished - 1 Mar 2018

Keywords

  • Autothermal reforming
  • Diesel
  • Interfaces
  • N-hexadecane
  • Nanoparticles
  • Rhodium catalysts
  • AL-BASED CATALYSTS

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