Heteroleptic Cu(II) iodoacetate complex: Appearance of halogen bonding in solid state

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Abstract

Heteroleptic complex of copper [Cu 2 (IOAc) 4 (3,5-ClPy) 2 ] (IOAc = iodoacetate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via I⋯Cl halogen bonding (3.501–3.549 Å) and its energies were estimated by theoretical methods (1.6–2.9 kcal/mol).

Original languageEnglish
Pages (from-to)221-224
Number of pages4
JournalInorganic Chemistry Communications
Volume105
DOIs
Publication statusPublished - 1 Jul 2019

Keywords

  • Carboxylate complexes
  • Copper
  • Crystal structure
  • Halogen bonding
  • Supramolecular contacts
  • HALIDES
  • INTERPLAY
  • S-ALKYL DERIVATIVES
  • BEHAVIOR
  • ACID. CRYSTAL-STRUCTURE
  • BINUCLEAR COPPER(II)-COMPLEX
  • LIGANDS
  • MAGNETIC-PROPERTIES
  • METAL-IONS
  • ARCHITECTURES

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