Heteroleptic Cu(II) iodoacetate complex: Appearance of halogen bonding in solid state

Sergey A. Adonin; Alexander S. Novikov; Maxim N. Sokolov; Vladimir P. Fedin

doi:10.1016/j.inoche.2019.05.018

Heteroleptic Cu(II) iodoacetate complex: Appearance of halogen bonding in solid state

Sergey A. Adonin, Alexander S. Novikov, Maxim N. Sokolov, Vladimir P. Fedin

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Heteroleptic complex of copper [Cu ₂ (IOAc) ₄ (3,5-ClPy) ₂ ] (IOAc = iodoacetate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via I⋯Cl halogen bonding (3.501–3.549 Å) and its energies were estimated by theoretical methods (1.6–2.9 kcal/mol).

Original language	English
Pages (from-to)	221-224
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	105
DOIs	https://doi.org/10.1016/j.inoche.2019.05.018
Publication status	Published - 1 Jul 2019

Keywords

Carboxylate complexes
Copper
Crystal structure
Halogen bonding
Supramolecular contacts
HALIDES
INTERPLAY
S-ALKYL DERIVATIVES
BEHAVIOR
ACID. CRYSTAL-STRUCTURE
BINUCLEAR COPPER(II)-COMPLEX
LIGANDS
MAGNETIC-PROPERTIES
METAL-IONS
ARCHITECTURES

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10.1016/j.inoche.2019.05.018

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@article{c98c88d4d12d44a393df2e083ef275fa,

title = "Heteroleptic Cu(II) iodoacetate complex: Appearance of halogen bonding in solid state",

abstract = " Heteroleptic complex of copper [Cu 2 (IOAc) 4 (3,5-ClPy) 2 ] (IOAc = iodoacetate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via I⋯Cl halogen bonding (3.501–3.549 {\AA}) and its energies were estimated by theoretical methods (1.6–2.9 kcal/mol). ",

keywords = "Carboxylate complexes, Copper, Crystal structure, Halogen bonding, Supramolecular contacts, HALIDES, INTERPLAY, S-ALKYL DERIVATIVES, BEHAVIOR, ACID. CRYSTAL-STRUCTURE, BINUCLEAR COPPER(II)-COMPLEX, LIGANDS, MAGNETIC-PROPERTIES, METAL-IONS, ARCHITECTURES",

author = "Adonin, {Sergey A.} and Novikov, {Alexander S.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",

year = "2019",

month = jul,

day = "1",

doi = "10.1016/j.inoche.2019.05.018",

language = "English",

volume = "105",

pages = "221--224",

journal = "Inorganic Chemistry Communication",

issn = "1387-7003",

publisher = "Elsevier",

}

TY - JOUR

T1 - Heteroleptic Cu(II) iodoacetate complex

T2 - Appearance of halogen bonding in solid state

AU - Adonin, Sergey A.

AU - Novikov, Alexander S.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Heteroleptic complex of copper [Cu 2 (IOAc) 4 (3,5-ClPy) 2 ] (IOAc = iodoacetate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via I⋯Cl halogen bonding (3.501–3.549 Å) and its energies were estimated by theoretical methods (1.6–2.9 kcal/mol).

AB - Heteroleptic complex of copper [Cu 2 (IOAc) 4 (3,5-ClPy) 2 ] (IOAc = iodoacetate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via I⋯Cl halogen bonding (3.501–3.549 Å) and its energies were estimated by theoretical methods (1.6–2.9 kcal/mol).

KW - Carboxylate complexes

KW - Copper

KW - Crystal structure

KW - Halogen bonding

KW - Supramolecular contacts

KW - HALIDES

KW - INTERPLAY

KW - S-ALKYL DERIVATIVES

KW - BEHAVIOR

KW - ACID. CRYSTAL-STRUCTURE

KW - BINUCLEAR COPPER(II)-COMPLEX

KW - LIGANDS

KW - MAGNETIC-PROPERTIES

KW - METAL-IONS

KW - ARCHITECTURES

UR - http://www.scopus.com/inward/record.url?scp=85065831886&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2019.05.018

DO - 10.1016/j.inoche.2019.05.018

M3 - Article

AN - SCOPUS:85065831886

VL - 105

SP - 221

EP - 224

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

Heteroleptic Cu(II) iodoacetate complex: Appearance of halogen bonding in solid state

Abstract

Keywords

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