Abstract
Heteroleptic complex of copper [Cu 2 (IOAc) 4 (3,5-ClPy) 2 ] (IOAc = iodoacetate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via I⋯Cl halogen bonding (3.501–3.549 Å) and its energies were estimated by theoretical methods (1.6–2.9 kcal/mol).
Original language | English |
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Pages (from-to) | 221-224 |
Number of pages | 4 |
Journal | Inorganic Chemistry Communications |
Volume | 105 |
DOIs | |
Publication status | Published - 1 Jul 2019 |
Keywords
- Carboxylate complexes
- Copper
- Crystal structure
- Halogen bonding
- Supramolecular contacts
- HALIDES
- INTERPLAY
- S-ALKYL DERIVATIVES
- BEHAVIOR
- ACID. CRYSTAL-STRUCTURE
- BINUCLEAR COPPER(II)-COMPLEX
- LIGANDS
- MAGNETIC-PROPERTIES
- METAL-IONS
- ARCHITECTURES
OECD FOS+WOS
- 1.04 CHEMICAL SCIENCES