Heteroleptic copper(II) complexes with 2-bromo-5-methylpyridine: Structures, features of non-covalent interactions and magnetic behavior

Sergey A. Adonin, Alexander S. Novikov, Katerina V. Chernova, Denis A. Vinnik, Sergey V. Taskaev, Ilya V. Korolkov, Ekaterina V. Ilyina, Alexander A. Pavlov, Valentin V. Novikov, Maxim N. Sokolov, Vladimir P. Fedin

Research output: Contribution to journalArticlepeer-review

Abstract

Isostructural complexes [Cu(2-Br-5-MePy)2X2] (2-Br-5-MePy = 2-bromo-5-methylpyridine, X = Cl (1), Br (2) were prepared and structurally characterized. Magnetic measurements reveal that both complexes demonstrate paramagnetic behavior.

Original languageEnglish
Article number119333
Number of pages4
JournalInorganica Chimica Acta
Volume502
DOIs
Publication statusPublished - 1 Mar 2020

Keywords

  • Copper
  • Magnetic properties
  • N-donor ligands
  • Supramolecular contacts
  • BR
  • VAN
  • DONOR
  • RADII
  • M-X
  • CL
  • HALOGEN BOND

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