Halogen bonding-assisted formation of one-dimensional polybromide–bromotellurate (2-ClPyH)2{[TeBr6](Br2)}

Andrey N. Usoltsev, Sergey A. Adonin, Alexander S. Novikov, Maxim N. Sokolov, Vladimir P. Fedin

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Supramolecular hybrid (2-ClPy)2{[TeBr6](Br2)} (1) was prepared by the reaction of TeO2, Br2 and 2-chloropyridinium in HBr. In the structure, mononuclear [TeBr6]2− units are connected by {Br2} linkers into 1D zigzag-shaped infinite chains. Energies of halogen bonding were estimated by theoretical methods (1.3–3.3 kcal/mol).

Original languageEnglish
Pages (from-to)1890-1898
Number of pages9
JournalJournal of Coordination Chemistry
Volume72
Issue number11
DOIs
Publication statusPublished - 3 Jun 2019

Keywords

  • halide complexes
  • halogen bonding
  • Polyhalide
  • supramolecular contacts
  • tellurium
  • FE CONTACTS
  • INTERPLAY
  • COMPLEXES
  • CRYSTAL-STRUCTURES
  • NETWORKS
  • NONCOVALENT INTERACTIONS
  • CENTERS
  • PREDICTION
  • HYDROGEN

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