Abstract

Reactions of 3-iodopyridine with [BiX 6 ] 3− solutions in HX (X = Cl, Br) results in chloro- and bromobismuthate complexes (3-IPyH) 2 {[BiCl 5 ]}·H 2 O (1) and (3-IPyH) 4 [Bi 2 Br 10 ]·2H 2 O. In both cases, halogen⋯halogen contacts play important role in formation of crystal packing; energies of these interactions were estimated by theoretical methods.

Original languageEnglish
Pages (from-to)137-140
Number of pages4
JournalPolyhedron
Volume166
DOIs
Publication statusPublished - 1 Jul 2019

Keywords

  • Bismuth
  • Halogen bonding
  • Halometalates
  • QTAIM
  • Supramolecular contacts
  • VAN
  • CYANAMIDE
  • COMPLEXES
  • IODIDE
  • NONCOVALENT INTERACTIONS
  • HYDROGEN
  • RADII
  • HYBRID
  • CHLORIDE

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