Abstract

Methylation of anionic cluster complexes [Re6Q8(CN)6]4- with ((CH3)3O)BF4 or CF3SO3CH3 afforded homoleptic isonitrile cluster complexes [Re6Q8(CH3NC)6]2+ (Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry, 1H NMR, 13C NMR, 14N NMR, 15N NMR, 77Se NMR, and 125Te NMR techniques, electrochemistry, TGA, and photophysical measurements.

Original languageEnglish
Pages (from-to)16338-16348
Number of pages11
JournalNew Journal of Chemistry
Volume43
Issue number41
DOIs
Publication statusPublished - 7 Nov 2019

Keywords

  • OCTAHEDRAL RHENIUM CLUSTER
  • PHOTOPHYSICAL PROPERTIES
  • LUMINESCENCE PROPERTIES
  • CHALCOGENIDE CLUSTERS
  • CRYSTAL-STRUCTURE
  • BUILDING-BLOCKS
  • EXCITED-STATE
  • COMPLEXES
  • REDOX
  • CORE

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