Facile mechanochemical synthesis of Co@NC catalysts for oxidative esterification of benzyl alcohol with methanol

Tatiana V. Astrakova; Vladimir I. Sobolev; Konstantin Yu Koltunov

doi:10.1016/j.catcom.2020.105952

Facile mechanochemical synthesis of Co@NC catalysts for oxidative esterification of benzyl alcohol with methanol

Tatiana V. Astrakova, Vladimir I. Sobolev, Konstantin Yu Koltunov

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A robust and solvent-free mechanochemical approach for the synthesis of cobalt–nitrogen–carbon nanocomposite by simple mixing of cobalt(II) salts, nitrogen-containing ligands and carbon black, followed by thermal treatment is suggested. The catalysts obtained were tested in the oxidative esterification of benzyl alcohol, demonstrating highly competitive performance.

Original language	English
Article number	105952
Number of pages	6
Journal	Catalysis Communications
Volume	137
DOIs	https://doi.org/10.1016/j.catcom.2020.105952
Publication status	Published - 5 Apr 2020

Keywords

Cobalt‑nitrogen‑carbon catalyst
Heterogeneous catalysis
Mechanochemical synthesis
Oxidative esterification
SELECTIVE OXIDATION
Cobalt-nitrogen-carbon catalyst
HYDROGENATION
ACTIVE-SITES
DOPED CARBON
NANOMATERIALS
NANOPARTICLES
DEHYDROGENATION
METAL
EFFICIENT
DISPERSED CO

OECD FOS+WOS

1.04 CHEMICAL SCIENCES

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10.1016/j.catcom.2020.105952

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title = "Facile mechanochemical synthesis of Co@NC catalysts for oxidative esterification of benzyl alcohol with methanol",

abstract = "A robust and solvent-free mechanochemical approach for the synthesis of cobalt–nitrogen–carbon nanocomposite by simple mixing of cobalt(II) salts, nitrogen-containing ligands and carbon black, followed by thermal treatment is suggested. The catalysts obtained were tested in the oxidative esterification of benzyl alcohol, demonstrating highly competitive performance.",

keywords = "Cobalt‑nitrogen‑carbon catalyst, Heterogeneous catalysis, Mechanochemical synthesis, Oxidative esterification, SELECTIVE OXIDATION, Cobalt-nitrogen-carbon catalyst, HYDROGENATION, ACTIVE-SITES, DOPED CARBON, NANOMATERIALS, NANOPARTICLES, DEHYDROGENATION, METAL, EFFICIENT, DISPERSED CO",

author = "Astrakova, {Tatiana V.} and Sobolev, {Vladimir I.} and Koltunov, {Konstantin Yu}",

year = "2020",

month = apr,

day = "5",

doi = "10.1016/j.catcom.2020.105952",

language = "English",

volume = "137",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier",

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TY - JOUR

T1 - Facile mechanochemical synthesis of Co@NC catalysts for oxidative esterification of benzyl alcohol with methanol

AU - Astrakova, Tatiana V.

AU - Sobolev, Vladimir I.

AU - Koltunov, Konstantin Yu

PY - 2020/4/5

Y1 - 2020/4/5

N2 - A robust and solvent-free mechanochemical approach for the synthesis of cobalt–nitrogen–carbon nanocomposite by simple mixing of cobalt(II) salts, nitrogen-containing ligands and carbon black, followed by thermal treatment is suggested. The catalysts obtained were tested in the oxidative esterification of benzyl alcohol, demonstrating highly competitive performance.

AB - A robust and solvent-free mechanochemical approach for the synthesis of cobalt–nitrogen–carbon nanocomposite by simple mixing of cobalt(II) salts, nitrogen-containing ligands and carbon black, followed by thermal treatment is suggested. The catalysts obtained were tested in the oxidative esterification of benzyl alcohol, demonstrating highly competitive performance.

KW - Cobalt‑nitrogen‑carbon catalyst

KW - Heterogeneous catalysis

KW - Mechanochemical synthesis

KW - Oxidative esterification

KW - SELECTIVE OXIDATION

KW - Cobalt-nitrogen-carbon catalyst

KW - HYDROGENATION

KW - ACTIVE-SITES

KW - DOPED CARBON

KW - NANOMATERIALS

KW - NANOPARTICLES

KW - DEHYDROGENATION

KW - METAL

KW - EFFICIENT

KW - DISPERSED CO

UR - http://www.scopus.com/inward/record.url?scp=85078971030&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2020.105952

DO - 10.1016/j.catcom.2020.105952

M3 - Article

AN - SCOPUS:85078971030

VL - 137

JO - Catalysis Communications

JF - Catalysis Communications

SN - 1566-7367

M1 - 105952

ER -

Facile mechanochemical synthesis of Co@NC catalysts for oxidative esterification of benzyl alcohol with methanol

Abstract

Keywords

OECD FOS+WOS

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