Experimental and numerical study of the structure of a premixed methyl decanoate/oxygen/argon glame

I. E. Gerasimov, D. A. Knyazkov, A. M. Dmitriev, L. V. Kuibida, A. G. Shmakov, O. P. Korobeinichev

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The structure of a premixed methyl decanoate/oxygen/argon flame stabilized on a flatflame burner at atmospheric pressure was studied by molecular beam mass spectrometry. The results of the experiment are compared with the results of numerical simulations using two different mechanisms of chemical reactions proposed in the literature. The main intermediate combustion products of methyl decanoate were identified by gas chromatography-mass spectrometry. Analysis of the primary stages of decomposition of methyl decanoate shows that reactions involving free radicals play a decisive role in its oxidation, which agrees well with the results of the experiments.

Original languageEnglish
Article number1
Pages (from-to)285-292
Number of pages8
JournalCombustion, Explosion and Shock Waves
Volume51
Issue number3
DOIs
Publication statusPublished - 29 May 2015

Keywords

  • flame structure
  • methyl decanoate
  • molecular beam mass spectrometry

OECD FOS+WOS

  • 1.07 OTHER NATURAL SCIENCES
  • 1.03 PHYSICAL SCIENCES AND ASTRONOMY
  • 1.04 CHEMICAL SCIENCES
  • 2.04 CHEMICAL ENGINEERING

State classification of scientific and technological information

  • 31.15 Physical chemistry

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