Effect of the anion nature on the structure of [RhL4Cl2]X (L=Py, γ- And β-picolines) complex salts

D. B. Vasil'chenko, A. B. Venediktov, I. A. Baidina, S. V. Korenev

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1 Citation (Scopus)

Abstract

An analysis is performed of the crystal structures of complex salts [RhL4Cl2]X (L=Py, γ- and β-picolines; X are different anions) in light of the effect induced by the nature of the anion X. It is shown that the intermolecular interactions between the anions play a key role in creating the general motif of the structure.

Original languageEnglish
Pages (from-to)310-316
Number of pages7
JournalJournal of Structural Chemistry
Volume56
Issue number2
DOIs
Publication statusPublished - 29 Mar 2015

Keywords

  • picoline
  • pyridine
  • rhodium
  • single-crystal X-ray diffraction

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