Double complex salts [Au(En)2][Ir(NO2)6] • nH2O (n = 0, 2), [Au(En)2][Ir(NO2)6]x[Rh(NO2)6]1–x • nH2O (x = 0.25, 0.5, 0.75): Synthesis, structure, thermal properties

E. V. Makotchenko; P. E. Plyusnin; Yu V. Shubin; I. A. Baidina; I. V. Korol’kov; L. A. Sheludyakova; S. V. Korenev

doi:10.1134/S0036023617010119

Double complex salts [Au(En)₂][Ir(NO₂)₆] • nH₂O (n = 0, 2), [Au(En)₂][Ir(NO₂)₆]_x[Rh(NO₂)₆]_1–x • nH₂O (x = 0.25, 0.5, 0.75): Synthesis, structure, thermal properties

E. V. Makotchenko, P. E. Plyusnin, Yu V. Shubin, I. A. Baidina, I. V. Korol’kov, L. A. Sheludyakova, S. V. Korenev

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The double complex salts [Au(En)₂][Ir(NO₂)₆] • 2H₂O (I) and [Au(En)₂][Ir(NO₂)₆] (II) and solid solutions [Au(En)₂][Ir(NO₂)₆]_x[Rh(NO₂)₆]_1–x • nH₂O, where x = 0.25, 0.5, 0.75, were prepared and characterized by powder X-ray diffraction, IR spectroscopy, elemental analysis, and DTA. The crystal structures were determined by X-ray diffraction. The thermal behavior of compounds under reducing atmosphere was studied. The final products of thermolysis were found to be two-phase mixtures consisting of nano-sized pure gold particles (~55 nm) and particles of Au–Ir–Rh solid solutions (~3 nm).

Original language	English
Pages (from-to)	12-21
Number of pages	10
Journal	Russian Journal of Inorganic Chemistry
Volume	62
Issue number	1
DOIs	https://doi.org/10.1134/S0036023617010119
Publication status	Published - 1 Jan 2017

Keywords

CRYSTAL-STRUCTURE
DEPOSITION PRECIPITATION
DECOMPOSITION
CATALYSTS
GOLD(III)
GOLD
RH
IR

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10.1134/S0036023617010119

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Makotchenko, E. V., Plyusnin, P. E., Shubin, Y. V., Baidina, I. A., Korol’kov, I. V., Sheludyakova, L. A., & Korenev, S. V. (2017). Double complex salts [Au(En)₂][Ir(NO₂)₆] • nH₂O (n = 0, 2), [Au(En)₂][Ir(NO₂)₆]_x[Rh(NO₂)₆]_1–x • nH₂O (x = 0.25, 0.5, 0.75): Synthesis, structure, thermal properties. Russian Journal of Inorganic Chemistry, 62(1), 12-21. https://doi.org/10.1134/S0036023617010119

@article{b2f4bd75cc0c434fa362fa1e3ecb865e,

title = "Double complex salts [Au(En)2][Ir(NO2)6] • nH2O (n = 0, 2), [Au(En)2][Ir(NO2)6]x[Rh(NO2)6]1–x • nH2O (x = 0.25, 0.5, 0.75): Synthesis, structure, thermal properties",

abstract = "The double complex salts [Au(En)2][Ir(NO2)6] • 2H2O (I) and [Au(En)2][Ir(NO2)6] (II) and solid solutions [Au(En)2][Ir(NO2)6]x[Rh(NO2)6]1–x • nH2O, where x = 0.25, 0.5, 0.75, were prepared and characterized by powder X-ray diffraction, IR spectroscopy, elemental analysis, and DTA. The crystal structures were determined by X-ray diffraction. The thermal behavior of compounds under reducing atmosphere was studied. The final products of thermolysis were found to be two-phase mixtures consisting of nano-sized pure gold particles (~55 nm) and particles of Au–Ir–Rh solid solutions (~3 nm).",

keywords = "CRYSTAL-STRUCTURE, DEPOSITION PRECIPITATION, DECOMPOSITION, CATALYSTS, GOLD(III), GOLD, RH, IR",

author = "Makotchenko, {E. V.} and Plyusnin, {P. E.} and Shubin, {Yu V.} and Baidina, {I. A.} and Korol{\textquoteright}kov, {I. V.} and Sheludyakova, {L. A.} and Korenev, {S. V.}",

year = "2017",

month = jan,

day = "1",

doi = "10.1134/S0036023617010119",

language = "English",

volume = "62",

pages = "12--21",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "1",

}

Makotchenko, EV, Plyusnin, PE , Shubin, YV, Baidina, IA, Korol’kov, IV, Sheludyakova, LA & Korenev, SV 2017, 'Double complex salts [Au(En)₂][Ir(NO₂)₆] • nH₂O (n = 0, 2), [Au(En)₂][Ir(NO₂)₆]_x[Rh(NO₂)₆]_1–x • nH₂O (x = 0.25, 0.5, 0.75): Synthesis, structure, thermal properties', Russian Journal of Inorganic Chemistry, vol. 62, no. 1, pp. 12-21. https://doi.org/10.1134/S0036023617010119

Double complex salts [Au(En)₂][Ir(NO₂)₆] • nH₂O (n = 0, 2), [Au(En)₂][Ir(NO₂)₆]_x[Rh(NO₂)₆]_1–x • nH₂O (x = 0.25, 0.5, 0.75) : Synthesis, structure, thermal properties. / Makotchenko, E. V.; Plyusnin, P. E.; Shubin, Yu V. et al.

In: Russian Journal of Inorganic Chemistry, Vol. 62, No. 1, 01.01.2017, p. 12-21.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Double complex salts [Au(En)2][Ir(NO2)6] • nH2O (n = 0, 2), [Au(En)2][Ir(NO2)6]x[Rh(NO2)6]1–x • nH2O (x = 0.25, 0.5, 0.75)

T2 - Synthesis, structure, thermal properties

AU - Makotchenko, E. V.

AU - Plyusnin, P. E.

AU - Shubin, Yu V.

AU - Baidina, I. A.

AU - Korol’kov, I. V.

AU - Sheludyakova, L. A.

AU - Korenev, S. V.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The double complex salts [Au(En)2][Ir(NO2)6] • 2H2O (I) and [Au(En)2][Ir(NO2)6] (II) and solid solutions [Au(En)2][Ir(NO2)6]x[Rh(NO2)6]1–x • nH2O, where x = 0.25, 0.5, 0.75, were prepared and characterized by powder X-ray diffraction, IR spectroscopy, elemental analysis, and DTA. The crystal structures were determined by X-ray diffraction. The thermal behavior of compounds under reducing atmosphere was studied. The final products of thermolysis were found to be two-phase mixtures consisting of nano-sized pure gold particles (~55 nm) and particles of Au–Ir–Rh solid solutions (~3 nm).

AB - The double complex salts [Au(En)2][Ir(NO2)6] • 2H2O (I) and [Au(En)2][Ir(NO2)6] (II) and solid solutions [Au(En)2][Ir(NO2)6]x[Rh(NO2)6]1–x • nH2O, where x = 0.25, 0.5, 0.75, were prepared and characterized by powder X-ray diffraction, IR spectroscopy, elemental analysis, and DTA. The crystal structures were determined by X-ray diffraction. The thermal behavior of compounds under reducing atmosphere was studied. The final products of thermolysis were found to be two-phase mixtures consisting of nano-sized pure gold particles (~55 nm) and particles of Au–Ir–Rh solid solutions (~3 nm).

KW - CRYSTAL-STRUCTURE

KW - DEPOSITION PRECIPITATION

KW - DECOMPOSITION

KW - CATALYSTS

KW - GOLD(III)

KW - GOLD

KW - RH

KW - IR

UR - http://www.scopus.com/inward/record.url?scp=85013167780&partnerID=8YFLogxK

U2 - 10.1134/S0036023617010119

DO - 10.1134/S0036023617010119

M3 - Article

AN - SCOPUS:85013167780

VL - 62

SP - 12

EP - 21

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 1

ER -

Double complex salts [Au(En)₂][Ir(NO₂)₆] • nH₂O (n = 0, 2), [Au(En)₂][Ir(NO₂)₆]_x[Rh(NO₂)₆]_1–x • nH₂O (x = 0.25, 0.5, 0.75): Synthesis, structure, thermal properties

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