Double complex [Mn2(C11H13N3O)6(H2O)2][Cr(NH3)2(NCS)4]4: Synthesis and crystal structure

T. G. Cherkasova, I. Yu Bagryanskaya, N. V. Pervukhina, A. L. Vornakov, E. V. Cherkasova, N. V. Kuratieva

Research output: Contribution to journalArticlepeer-review

Abstract

[Mn2(C11H13N3O)6(H2O)2][Cr(NH3)2(NCS)4]4 (I) has been synthesized by the reaction between MnCl2 · H2O, NH4[Cr(NH3)2(NCS)4] · 0.5H2O and 4-aminoantipyrine (C11H13N3O) in an aqueous solution, and its structure has been determined by IR spectroscopy and X-ray diffraction. Crystals of complex I are triclinic, space group P1 ¯ , Z = 1, a = 13.2378(5) Å, b = 15.7796(5) Å, c = 16.7703(6) Å, α = 83.194(2)°, β = 75.874(2)°, γ = 66.529(1)°, V = 3115.2(2) Å3, and ρcalcd = 1.407 g/cm3.

Original languageEnglish
Pages (from-to)182-186
Number of pages5
JournalRussian Journal of Inorganic Chemistry
Volume62
Issue number2
DOIs
Publication statusPublished - 1 Feb 2017

Keywords

  • CU(II)/CR(III) COMPLEXES
  • REINECKES SALT
  • COPPER-POWDER
  • X-RAY

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