Direct measurement of ultrafast intersystem crossing time for the PtIVBr62− complex

Alexey A. Melnikov, Ivan P. Pozdnyakov, Sergey V. Chekalin, Evgeni M. Glebov

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The time of ultrafast intersystem crossing for the PtIVBr62– complex in aqueous solution was measured by a fluorescence up-conversion technique. The corresponding time constant (140 ± 40 fs) is in agreement with that estimated from previous ultrafast transient absorption measurements and with the reported results of theoretical calculations.

Original languageEnglish
Pages (from-to)509-511
Number of pages3
JournalMendeleev Communications
Volume30
Issue number4
DOIs
Publication statusPublished - 1 Jul 2020

Keywords

  • fluorescence up-conversion
  • PtBr complex
  • ultrafast dynamics
  • ultrafast intersystem crossing
  • PHOTOCHEMICAL PROCESSES
  • PtBr62- complex
  • PHOTOPHYSICS
  • DYNAMICS
  • FEMTOSECOND FLUORESCENCE

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