DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks

S. G. Kozlova; I. V. Mirzaeva; M. R. Ryzhikov

doi:10.1016/j.ccr.2018.07.008

DABCO molecule in the M₂(C₈H₄O₄)₂·C₆H₁₂N₂ (M = Co, Ni, Cu, Zn) metal-organic frameworks

S. G. Kozlova, I. V. Mirzaeva, M. R. Ryzhikov

Research output: Contribution to journal › Review article › peer-review

13 Citations (Scopus)

Abstract

The review reports recent progress in experimental and theoretical studies of structure and properties of the C₆H₁₂N₂ molecule (DABCO) in metal-organic frameworks M₂(C₈H₄O₄)₂ C₆H₁₂N₂, where M = Co, Ni, Cu, Zn (M-DMOFs), as well as in the gas and crystalline phases. M-DMOFs belong to a new class of compounds which are considered promising materials for sorption, catalysis, selective separation, and demonstrate other remarkable properties. We review recent research on phase transitions and effect of guest molecules on properties of M-DMOFs. Thermodynamic and nuclear magnetic resonance studies of M-DMOFs indicate quantum tunneling between twisted forms (chiral isomers) of the DABCO molecule with D₃ symmetry, which stops at certain low temperature. This opens an opportunity for study and control of balance between chiral isomers.

Original language	English
Pages (from-to)	62-74
Number of pages	13
Journal	Coordination Chemistry Reviews
Volume	376
DOIs	https://doi.org/10.1016/j.ccr.2018.07.008
Publication status	Published - 1 Dec 2018

Keywords

DABCO
M-DMOF
Mobility
Parity violation
Phase transition
Quantum tunneling
THERMODYNAMIC PROPERTIES
PHASE-TRANSITIONS
CRYSTAL-STRUCTURE
VIBRATIONAL-SPECTRA
BOSE-EINSTEIN CONDENSATION
CATALYZED SUZUKI-MIYAURA
HEAT-CAPACITIES
PARITY-SYMMETRY-BREAKING
NUCLEAR-QUADRUPOLE-RESONANCE
D-ALANINE

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10.1016/j.ccr.2018.07.008

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title = "DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks",

abstract = "The review reports recent progress in experimental and theoretical studies of structure and properties of the C6H12N2 molecule (DABCO) in metal-organic frameworks M2(C8H4O4)2 C6H12N2, where M = Co, Ni, Cu, Zn (M-DMOFs), as well as in the gas and crystalline phases. M-DMOFs belong to a new class of compounds which are considered promising materials for sorption, catalysis, selective separation, and demonstrate other remarkable properties. We review recent research on phase transitions and effect of guest molecules on properties of M-DMOFs. Thermodynamic and nuclear magnetic resonance studies of M-DMOFs indicate quantum tunneling between twisted forms (chiral isomers) of the DABCO molecule with D3 symmetry, which stops at certain low temperature. This opens an opportunity for study and control of balance between chiral isomers.",

keywords = "DABCO, M-DMOF, Mobility, Parity violation, Phase transition, Quantum tunneling, THERMODYNAMIC PROPERTIES, PHASE-TRANSITIONS, CRYSTAL-STRUCTURE, VIBRATIONAL-SPECTRA, BOSE-EINSTEIN CONDENSATION, CATALYZED SUZUKI-MIYAURA, HEAT-CAPACITIES, PARITY-SYMMETRY-BREAKING, NUCLEAR-QUADRUPOLE-RESONANCE, D-ALANINE",

author = "Kozlova, {S. G.} and Mirzaeva, {I. V.} and Ryzhikov, {M. R.}",

year = "2018",

month = dec,

day = "1",

doi = "10.1016/j.ccr.2018.07.008",

language = "English",

volume = "376",

pages = "62--74",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

publisher = "Elsevier",

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AU - Kozlova, S. G.

AU - Mirzaeva, I. V.

AU - Ryzhikov, M. R.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - The review reports recent progress in experimental and theoretical studies of structure and properties of the C6H12N2 molecule (DABCO) in metal-organic frameworks M2(C8H4O4)2 C6H12N2, where M = Co, Ni, Cu, Zn (M-DMOFs), as well as in the gas and crystalline phases. M-DMOFs belong to a new class of compounds which are considered promising materials for sorption, catalysis, selective separation, and demonstrate other remarkable properties. We review recent research on phase transitions and effect of guest molecules on properties of M-DMOFs. Thermodynamic and nuclear magnetic resonance studies of M-DMOFs indicate quantum tunneling between twisted forms (chiral isomers) of the DABCO molecule with D3 symmetry, which stops at certain low temperature. This opens an opportunity for study and control of balance between chiral isomers.

AB - The review reports recent progress in experimental and theoretical studies of structure and properties of the C6H12N2 molecule (DABCO) in metal-organic frameworks M2(C8H4O4)2 C6H12N2, where M = Co, Ni, Cu, Zn (M-DMOFs), as well as in the gas and crystalline phases. M-DMOFs belong to a new class of compounds which are considered promising materials for sorption, catalysis, selective separation, and demonstrate other remarkable properties. We review recent research on phase transitions and effect of guest molecules on properties of M-DMOFs. Thermodynamic and nuclear magnetic resonance studies of M-DMOFs indicate quantum tunneling between twisted forms (chiral isomers) of the DABCO molecule with D3 symmetry, which stops at certain low temperature. This opens an opportunity for study and control of balance between chiral isomers.

KW - DABCO

KW - M-DMOF

KW - Mobility

KW - Parity violation

KW - Phase transition

KW - Quantum tunneling

KW - THERMODYNAMIC PROPERTIES

KW - PHASE-TRANSITIONS

KW - CRYSTAL-STRUCTURE

KW - VIBRATIONAL-SPECTRA

KW - BOSE-EINSTEIN CONDENSATION

KW - CATALYZED SUZUKI-MIYAURA

KW - HEAT-CAPACITIES

KW - PARITY-SYMMETRY-BREAKING

KW - NUCLEAR-QUADRUPOLE-RESONANCE

KW - D-ALANINE

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U2 - 10.1016/j.ccr.2018.07.008

DO - 10.1016/j.ccr.2018.07.008

M3 - Review article

AN - SCOPUS:85051390598

VL - 376

SP - 62

EP - 74

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

SN - 0010-8545

ER -

DABCO molecule in the M₂(C₈H₄O₄)₂·C₆H₁₂N₂ (M = Co, Ni, Cu, Zn) metal-organic frameworks

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DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks

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DABCO molecule in the M₂(C₈H₄O₄)₂·C₆H₁₂N₂ (M = Co, Ni, Cu, Zn) metal-organic frameworks