Crystallographic Analysis of the Structure of LaBiI6·13H2O and NdBiI6·13H2O. Sublattice of Iodine Atoms: A Common Skeleton of the Structures

S. V. Borisov, N. V. Pervukhina, S. A. Magarill

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2 Citations (Scopus)

Abstract

The crystallographic analysis of the recently determined structures of LaBiI6·13H2O and NdBiI6·13H2O reveals that their common basis is a sublattice of iodine anions built of coherently assembled octahedral I6 fragments. The relationship between the parameters of orthorhombic and monoclinic unit cells of these structures is shown and their symmetry features are discussed.

Original languageEnglish
Pages (from-to)1387-1391
Number of pages5
JournalJournal of Structural Chemistry
Volume59
Issue number6
DOIs
Publication statusPublished - 1 Nov 2018

Keywords

  • crystallographic analysis, coherent assembly, sublattice of iodine anions, packing of complex [Ln(HO)] and [BiI] ions
  • packing of complex [Ln(H2O)(9)](3+) and [BiI6](3-) ions
  • crystallographic analysis
  • sublattice of iodine anions
  • coherent assembly

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