Crystallographic Analysis of the Structure of LaBiI6·13H2O and NdBiI6·13H2O. Sublattice of Iodine Atoms: A Common Skeleton of the Structures

S. V. Borisov; N. V. Pervukhina; S. A. Magarill

doi:10.1134/S0022476618060197

Crystallographic Analysis of the Structure of LaBiI₆·13H₂O and NdBiI₆·13H₂O. Sublattice of Iodine Atoms: A Common Skeleton of the Structures

S. V. Borisov, N. V. Pervukhina, S. A. Magarill

Department of Physics

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The crystallographic analysis of the recently determined structures of LaBiI₆·13H₂O and NdBiI₆·13H₂O reveals that their common basis is a sublattice of iodine anions built of coherently assembled octahedral I₆ fragments. The relationship between the parameters of orthorhombic and monoclinic unit cells of these structures is shown and their symmetry features are discussed.

Original language	English
Pages (from-to)	1387-1391
Number of pages	5
Journal	Journal of Structural Chemistry
Volume	59
Issue number	6
DOIs	https://doi.org/10.1134/S0022476618060197
Publication status	Published - 1 Nov 2018

Keywords

crystallographic analysis, coherent assembly, sublattice of iodine anions, packing of complex [Ln(HO)] and [BiI] ions
packing of complex [Ln(H2O)(9)](3+) and [BiI6](3-) ions
crystallographic analysis
sublattice of iodine anions
coherent assembly

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10.1134/S0022476618060197

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title = "Crystallographic Analysis of the Structure of LaBiI6·13H2O and NdBiI6·13H2O. Sublattice of Iodine Atoms: A Common Skeleton of the Structures",

abstract = "The crystallographic analysis of the recently determined structures of LaBiI6·13H2O and NdBiI6·13H2O reveals that their common basis is a sublattice of iodine anions built of coherently assembled octahedral I6 fragments. The relationship between the parameters of orthorhombic and monoclinic unit cells of these structures is shown and their symmetry features are discussed.",

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T2 - A Common Skeleton of the Structures

AU - Borisov, S. V.

AU - Pervukhina, N. V.

AU - Magarill, S. A.

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AB - The crystallographic analysis of the recently determined structures of LaBiI6·13H2O and NdBiI6·13H2O reveals that their common basis is a sublattice of iodine anions built of coherently assembled octahedral I6 fragments. The relationship between the parameters of orthorhombic and monoclinic unit cells of these structures is shown and their symmetry features are discussed.

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KW - packing of complex [Ln(H2O)(9)](3+) and [BiI6](3-) ions

KW - crystallographic analysis

KW - sublattice of iodine anions

KW - coherent assembly

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