Crystal structures of [M(Еn)3](ReO4)2 (M = Ni, Zn)

S. P. Khranenko, E. A. Bykova, A. V. Zadesenets, S. A. Gromilov

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The structures of two isostructural phases of [M(Еn)3](ReO4)2 (M = Ni, Zn; Еn is ethylenediamine) are studied. The crystal structures belong to the triclinic system, but demonstrate a pseudohexagonal packing motif. It is shown that the product of thermal decomposition of [Zn(Еn)3](ReO4)2 (hydrogen atmosphere, 400 °C) is a homogeneous mixture of nanocrystalline zinc and rhenium powders with coherent scattering regions of ~30 nm.

Original languageEnglish
Pages (from-to)90-96
Number of pages7
JournalJournal of Structural Chemistry
Volume58
Issue number1
DOIs
Publication statusPublished - 1 Jan 2017

Keywords

  • crystal chemistry
  • ethylenediamine
  • nickel
  • rhenium
  • single crystal X-ray diffraction study
  • zinc
  • THERMOLYSIS
  • THERMAL-PROPERTIES
  • SOLID-SOLUTIONS
  • SALTS

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