Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)

S. A. Adonin; M. N. Sokolov; V. P. Fedin

doi:10.1134/S0022476619100111

Crystal Structures of Bromobismuthate Complexes ((3-MePy)₂C₂)₄[Bi₂Br₁₁][BiBr₆] and (3-MePy)₂C₂[Bi₂Br₁₁](Br₃)

S. A. Adonin, M. N. Sokolov, V. P. Fedin

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

By the reaction of a [BiX₆]³⁻ solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)₂C₂Br₂) the bromobismuthate complex ((3-MePy)₂C₂)₄[Bi₂Br₁₁][BiBr₆] (1) is obtained, which, when kept in the Br₂ solution in HBr, transforms into ((3-MePy)₂C₂)₃ [Bi₂Br₁₁](Br₃) (2). Compounds 1 and 2 are characterized by single crystal XRD.

Original language	English
Pages (from-to)	1655-1659
Number of pages	5
Journal	Journal of Structural Chemistry
Volume	60
Issue number	10
DOIs	https://doi.org/10.1134/S0022476619100111
Publication status	Published - 1 Oct 2019

Keywords

bismuth
halide complexes
polyhalides
polynuclear complexes

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10.1134/S0022476619100111

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title = "Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)",

abstract = "By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.",

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author = "Adonin, {S. A.} and Sokolov, {M. N.} and Fedin, {V. P.}",

year = "2019",

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T1 - Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)

AU - Adonin, S. A.

AU - Sokolov, M. N.

AU - Fedin, V. P.

PY - 2019/10/1

Y1 - 2019/10/1

N2 - By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.

AB - By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.

KW - bismuth

KW - halide complexes

KW - polyhalides

KW - polynuclear complexes

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