Abstract
By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.
Original language | English |
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Pages (from-to) | 1655-1659 |
Number of pages | 5 |
Journal | Journal of Structural Chemistry |
Volume | 60 |
Issue number | 10 |
DOIs | |
Publication status | Published - 1 Oct 2019 |
Keywords
- bismuth
- halide complexes
- polyhalides
- polynuclear complexes