Crystal Structures of Bi- and Tetranuclear Halide Complexes of Bi(III) with 2,6-Dimethyl- and 2,4,6-Trimethylpyridine Cations

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Abstract

Bi- and tetranuclear complexes (2,6-MePyH)6[Bi4Cl18]·6H2O (1), (2,6-MePyH)4[Bi2Br10]·2H2O (2) and (2,4,6-MePyH)3[Bi2Br9] (3) are obtained by the reactions of [BiX6]3− (X = Cl, Br) solutions with the salts of corresponding substituted pyridines. Compounds 1–3 are characterized by the XRD method.

Original languageEnglish
Pages (from-to)1799-1803
Number of pages5
JournalJournal of Structural Chemistry
Volume60
Issue number11
DOIs
Publication statusPublished - 1 Nov 2019

Keywords

  • bismuth
  • halide complexes
  • polynuclear complexes
  • pyridines
  • HIRSHFELD SURFACE-ANALYSIS
  • SIZE
  • OPTICAL-PROPERTIES
  • CHLOROBISMUTHATE(III)
  • DIVERSITY
  • HYBRID
  • VIOLOGEN

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