Crystal structure of lithium, potassium, and calcium complexes with β-cyclodextrine

E. I. Koshevoi; D. G. Samsonenko; P. V. Dorovatovskii; V. A. Lazarenko; V. P. Fedin

doi:10.1134/S0022476621040090

Crystal structure of lithium, potassium, and calcium complexes with β-cyclodextrine

E. I. Koshevoi, D. G. Samsonenko, P. V. Dorovatovskii, V. A. Lazarenko, V. P. Fedin

Research output: Contribution to journal › Article › peer-review

Abstract

Three new coordination compounds are obtained in the reaction of aqueous solutions of lithium and potassium hydroxides or calcium chloride with β-cyclodextrine. Their compositions and structures are determined by single crystal X-ray diffraction. The lithium and potassium complexes represent metal-organic coordination polymers with chain (Li) and layered (K) structures. The crystal structure of the calcium compound is a packing of discrete complexes.

Original language	English
Pages (from-to)	577-584
Number of pages	8
Journal	Journal of Structural Chemistry
Volume	62
Issue number	4
DOIs	https://doi.org/10.1134/S0022476621040090
Publication status	Published - Apr 2021

Keywords

calcium complexes
crystal structure
lithium complexes
metal-organic coordination polymer
potassium complexes
β-cyclodextrine

OECD FOS+WOS

2.05 MATERIALS ENGINEERING
1.04 CHEMICAL SCIENCES

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title = "Crystal structure of lithium, potassium, and calcium complexes with β-cyclodextrine",

abstract = "Three new coordination compounds are obtained in the reaction of aqueous solutions of lithium and potassium hydroxides or calcium chloride with β-cyclodextrine. Their compositions and structures are determined by single crystal X-ray diffraction. The lithium and potassium complexes represent metal-organic coordination polymers with chain (Li) and layered (K) structures. The crystal structure of the calcium compound is a packing of discrete complexes.",

keywords = "calcium complexes, crystal structure, lithium complexes, metal-organic coordination polymer, potassium complexes, β-cyclodextrine",

author = "Koshevoi, {E. I.} and Samsonenko, {D. G.} and Dorovatovskii, {P. V.} and Lazarenko, {V. A.} and Fedin, {V. P.}",

note = "Funding Information: Diffraction data for β-CD–Li and β-CD–K compounds were obtained using synchrotron radiation and the study was supported by the Russian Science Foundation (project No. 19-73-20087). Funding Information: The work was supported by RFBR (project No. 18-29-04001). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2021",

month = apr,

doi = "10.1134/S0022476621040090",

language = "English",

volume = "62",

pages = "577--584",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

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T1 - Crystal structure of lithium, potassium, and calcium complexes with β-cyclodextrine

AU - Koshevoi, E. I.

AU - Samsonenko, D. G.

AU - Dorovatovskii, P. V.

AU - Lazarenko, V. A.

AU - Fedin, V. P.

N1 - Funding Information: Diffraction data for β-CD–Li and β-CD–K compounds were obtained using synchrotron radiation and the study was supported by the Russian Science Foundation (project No. 19-73-20087). Funding Information: The work was supported by RFBR (project No. 18-29-04001). Publisher Copyright: © 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/4

Y1 - 2021/4

N2 - Three new coordination compounds are obtained in the reaction of aqueous solutions of lithium and potassium hydroxides or calcium chloride with β-cyclodextrine. Their compositions and structures are determined by single crystal X-ray diffraction. The lithium and potassium complexes represent metal-organic coordination polymers with chain (Li) and layered (K) structures. The crystal structure of the calcium compound is a packing of discrete complexes.

AB - Three new coordination compounds are obtained in the reaction of aqueous solutions of lithium and potassium hydroxides or calcium chloride with β-cyclodextrine. Their compositions and structures are determined by single crystal X-ray diffraction. The lithium and potassium complexes represent metal-organic coordination polymers with chain (Li) and layered (K) structures. The crystal structure of the calcium compound is a packing of discrete complexes.

KW - calcium complexes

KW - crystal structure

KW - lithium complexes

KW - metal-organic coordination polymer

KW - potassium complexes

KW - β-cyclodextrine

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U2 - 10.1134/S0022476621040090

DO - 10.1134/S0022476621040090

M3 - Article

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SP - 577

EP - 584

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

Crystal structure of lithium, potassium, and calcium complexes with β-cyclodextrine

Abstract

Keywords

OECD FOS+WOS

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