Crystal Structure of Binuclear Cobalt Complexes [(CpCo)221η2-S2)2] and [(CpCo)2212-Se2)2]

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Abstract

Binuclear cobalt complexes [(CpCo)2212-S2)2] (1) (Cp = η5-1,2,4-tris(tert-butyl)cyclopentadienide) and [(CpCo)2212-Se2)2] (2) are obtained by the interaction of [(CpCo)2(μ-η44-C7H8)] with excess sulfur or selenium respectively. The structures of the complexes are determined by single crystal X-ray diffraction.

Original languageEnglish
Pages (from-to)136-139
Number of pages4
JournalJournal of Structural Chemistry
Volume59
Issue number1
DOIs
Publication statusPublished - 1 Jan 2018

Keywords

  • binuclear complexes
  • cobalt
  • crystal structure
  • selenium
  • sulfur
  • synthesis
  • ARENE
  • LIGANDS
  • REACTIVITY
  • TRIPLE-DECKER
  • RICH

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