Crystal Structure of Binuclear Cobalt Complexes [(CpCo)2(μ2-η1η2-S2)2] and [(CpCo)2(μ2-η1:η2-Se2)2]

M. Yu Afonin; T. S. Sukhikh; S. N. Konchenko

doi:10.1134/S0022476618010201

Crystal Structure of Binuclear Cobalt Complexes [(CpCo)₂(μ₂-η¹η²-S₂)₂] and [(CpCo)₂(μ₂-η¹:η²-Se₂)₂]

M. Yu Afonin, T. S. Sukhikh, S. N. Konchenko

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Binuclear cobalt complexes [(CpCo)₂(μ₂-η¹:η²-S₂)₂] (1) (Cp = η⁵-1,2,4-tris(tert-butyl)cyclopentadienide) and [(CpCo)₂(μ₂-η¹:η²-Se₂)₂] (2) are obtained by the interaction of [(CpCo)₂(μ-η⁴:η⁴-C₇H₈)] with excess sulfur or selenium respectively. The structures of the complexes are determined by single crystal X-ray diffraction.

Original language	English
Pages (from-to)	136-139
Number of pages	4
Journal	Journal of Structural Chemistry
Volume	59
Issue number	1
DOIs	https://doi.org/10.1134/S0022476618010201
Publication status	Published - 1 Jan 2018

Keywords

binuclear complexes
cobalt
crystal structure
selenium
sulfur
synthesis
ARENE
LIGANDS
REACTIVITY
TRIPLE-DECKER
RICH

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10.1134/S0022476618010201

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title = "Crystal Structure of Binuclear Cobalt Complexes [(CpCo)2(μ2-η1η2-S2)2] and [(CpCo)2(μ2-η1:η2-Se2)2]",

abstract = "Binuclear cobalt complexes [(CpCo)2(μ2-η1:η2-S2)2] (1) (Cp = η5-1,2,4-tris(tert-butyl)cyclopentadienide) and [(CpCo)2(μ2-η1:η2-Se2)2] (2) are obtained by the interaction of [(CpCo)2(μ-η4:η4-C7H8)] with excess sulfur or selenium respectively. The structures of the complexes are determined by single crystal X-ray diffraction.",

keywords = "binuclear complexes, cobalt, crystal structure, selenium, sulfur, synthesis, ARENE, LIGANDS, REACTIVITY, TRIPLE-DECKER, RICH",

author = "Afonin, {M. Yu} and Sukhikh, {T. S.} and Konchenko, {S. N.}",

year = "2018",

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T1 - Crystal Structure of Binuclear Cobalt Complexes [(CpCo)2(μ2-η1η2-S2)2] and [(CpCo)2(μ2-η1:η2-Se2)2]

AU - Afonin, M. Yu

AU - Sukhikh, T. S.

AU - Konchenko, S. N.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Binuclear cobalt complexes [(CpCo)2(μ2-η1:η2-S2)2] (1) (Cp = η5-1,2,4-tris(tert-butyl)cyclopentadienide) and [(CpCo)2(μ2-η1:η2-Se2)2] (2) are obtained by the interaction of [(CpCo)2(μ-η4:η4-C7H8)] with excess sulfur or selenium respectively. The structures of the complexes are determined by single crystal X-ray diffraction.

AB - Binuclear cobalt complexes [(CpCo)2(μ2-η1:η2-S2)2] (1) (Cp = η5-1,2,4-tris(tert-butyl)cyclopentadienide) and [(CpCo)2(μ2-η1:η2-Se2)2] (2) are obtained by the interaction of [(CpCo)2(μ-η4:η4-C7H8)] with excess sulfur or selenium respectively. The structures of the complexes are determined by single crystal X-ray diffraction.

KW - binuclear complexes

KW - cobalt

KW - crystal structure

KW - selenium

KW - sulfur

KW - synthesis

KW - ARENE

KW - LIGANDS

KW - REACTIVITY

KW - TRIPLE-DECKER

KW - RICH

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DO - 10.1134/S0022476618010201

M3 - Article

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SP - 136

EP - 139

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

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