Crystal structure and EPR spectra of (Bu4N)2[V(dmit)3]

Ya S. Fomenko; A. L. Gushchin; V. A. Nadolinny; P. A. Abramov; M. N. Sokolov

doi:10.1134/S0022476617050158

Crystal structure and EPR spectra of (Bu₄N)₂[V(dmit)₃]

Ya S. Fomenko, A. L. Gushchin, V. A. Nadolinny, P. A. Abramov, M. N. Sokolov

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Abstract

The tris-chelate complex of vanadium(IV) (Bu₄N)₂[V(dmit)₃] is prepared from VCl₃ and (Bu₄N)₂[Zn(dmit)₂] (dmit = isotrithionedithiolate C₃S₅ ^2–) and characterized by single crystal XRD and mass spectrometry. The complex crystallizes in the space group Pna2₁ and has a distorted octahedral environment of vanadium. The complex is paramagnetic and gives a characteristic EPR spectrum in both solution and solid phase. The g factors and hyperfine interaction constants are determined.

Original language	English
Pages (from-to)	964-969
Number of pages	6
Journal	Journal of Structural Chemistry
Volume	58
Issue number	5
DOIs	https://doi.org/10.1134/S0022476617050158
Publication status	Published - 1 Sep 2017

Keywords

crystal structure
dithiolate complexes
EPR spectra
vanadium

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10.1134/S0022476617050158

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title = "Crystal structure and EPR spectra of (Bu4N)2[V(dmit)3]",

abstract = "The tris-chelate complex of vanadium(IV) (Bu4N)2[V(dmit)3] is prepared from VCl3 and (Bu4N)2[Zn(dmit)2] (dmit = isotrithionedithiolate C3S5 2–) and characterized by single crystal XRD and mass spectrometry. The complex crystallizes in the space group Pna21 and has a distorted octahedral environment of vanadium. The complex is paramagnetic and gives a characteristic EPR spectrum in both solution and solid phase. The g factors and hyperfine interaction constants are determined.",

keywords = "crystal structure, dithiolate complexes, EPR spectra, vanadium",

author = "Fomenko, {Ya S.} and Gushchin, {A. L.} and Nadolinny, {V. A.} and Abramov, {P. A.} and Sokolov, {M. N.}",

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T1 - Crystal structure and EPR spectra of (Bu4N)2[V(dmit)3]

AU - Fomenko, Ya S.

AU - Gushchin, A. L.

AU - Nadolinny, V. A.

AU - Abramov, P. A.

AU - Sokolov, M. N.

PY - 2017/9/1

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N2 - The tris-chelate complex of vanadium(IV) (Bu4N)2[V(dmit)3] is prepared from VCl3 and (Bu4N)2[Zn(dmit)2] (dmit = isotrithionedithiolate C3S5 2–) and characterized by single crystal XRD and mass spectrometry. The complex crystallizes in the space group Pna21 and has a distorted octahedral environment of vanadium. The complex is paramagnetic and gives a characteristic EPR spectrum in both solution and solid phase. The g factors and hyperfine interaction constants are determined.

AB - The tris-chelate complex of vanadium(IV) (Bu4N)2[V(dmit)3] is prepared from VCl3 and (Bu4N)2[Zn(dmit)2] (dmit = isotrithionedithiolate C3S5 2–) and characterized by single crystal XRD and mass spectrometry. The complex crystallizes in the space group Pna21 and has a distorted octahedral environment of vanadium. The complex is paramagnetic and gives a characteristic EPR spectrum in both solution and solid phase. The g factors and hyperfine interaction constants are determined.

KW - crystal structure

KW - dithiolate complexes

KW - EPR spectra

KW - vanadium

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DO - 10.1134/S0022476617050158

M3 - Article

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VL - 58

SP - 964

EP - 969

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

Crystal structure and EPR spectra of (Bu₄N)₂[V(dmit)₃]

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Keywords

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