Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)2[O(H)Me]4 (M = Ni, Co)

R. R. Datchuk; A. A. Grineva; M. A. Uvarova; I. A. Yakushev; Ya V. Zubavichus; S. E. Nefedov

doi:10.1134/S0036023619100036

Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)₂[O(H)Me]₄ (M = Ni, Co)

R. R. Datchuk, A. A. Grineva, M. A. Uvarova, I. A. Yakushev, Ya V. Zubavichus, S. E. Nefedov

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The slow diffusion of a γ,γ′-dipyridyl adduct solution in methanol into a methanol solution of the adduct M[(OOCPh]₂[O(H)Me]₄ (1) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh)₂[O(H)Me]₂}_n (M = Ni (2), green; Co (3), orange) and {(dipy)₂Co₂(µ-OOCPh)₂(η²-OOCPh)₂ ⋅ MeOH}_n (4), pink). Orange polymer 3 was the only product when the initial reagents were diluted three times, and their diffusion was performed at 5°C. Synthesized polymers 2–4 were studied by chemical and X-ray diffraction analyses and IR spectroscopy.

Original language	English
Pages (from-to)	1220-1228
Number of pages	9
Journal	Russian Journal of Inorganic Chemistry
Volume	64
Issue number	10
DOIs	https://doi.org/10.1134/S0036023619100036
Publication status	Published - 1 Oct 2019
Externally published	Yes

Keywords

N-donor
nickel and cobalt benzoates
synthesis
X-ray diffraction analysis
METHANOL
METAL-ORGANIC FRAMEWORKS
COPPER(II)
COMPLEXES
ZN(II)
CO(II)
ADDUCT
NI(II)

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10.1134/S0036023619100036

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@article{8f014587cfa4490da3c72100720b654c,

title = "Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)2[O(H)Me]4 (M = Ni, Co)",

abstract = "The slow diffusion of a γ,γ′-dipyridyl adduct solution in methanol into a methanol solution of the adduct M[(OOCPh]2[O(H)Me]4 (1) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh)2[O(H)Me]2}n (M = Ni (2), green; Co (3), orange) and {(dipy)2Co2(µ-OOCPh)2(η2-OOCPh)2 ⋅ MeOH}n (4), pink). Orange polymer 3 was the only product when the initial reagents were diluted three times, and their diffusion was performed at 5°C. Synthesized polymers 2–4 were studied by chemical and X-ray diffraction analyses and IR spectroscopy.",

keywords = "N-donor, nickel and cobalt benzoates, synthesis, X-ray diffraction analysis, METHANOL, METAL-ORGANIC FRAMEWORKS, COPPER(II), COMPLEXES, ZN(II), CO(II), ADDUCT, NI(II)",

author = "Datchuk, {R. R.} and Grineva, {A. A.} and Uvarova, {M. A.} and Yakushev, {I. A.} and Zubavichus, {Ya V.} and Nefedov, {S. E.}",

year = "2019",

month = oct,

day = "1",

doi = "10.1134/S0036023619100036",

language = "English",

volume = "64",

pages = "1220--1228",

journal = "Russian Journal of Inorganic Chemistry",

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publisher = "Maik Nauka-Interperiodica Publishing",

number = "10",

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TY - JOUR

T1 - Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)2[O(H)Me]4 (M = Ni, Co)

AU - Datchuk, R. R.

AU - Grineva, A. A.

AU - Uvarova, M. A.

AU - Yakushev, I. A.

AU - Zubavichus, Ya V.

AU - Nefedov, S. E.

PY - 2019/10/1

Y1 - 2019/10/1

N2 - The slow diffusion of a γ,γ′-dipyridyl adduct solution in methanol into a methanol solution of the adduct M[(OOCPh]2[O(H)Me]4 (1) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh)2[O(H)Me]2}n (M = Ni (2), green; Co (3), orange) and {(dipy)2Co2(µ-OOCPh)2(η2-OOCPh)2 ⋅ MeOH}n (4), pink). Orange polymer 3 was the only product when the initial reagents were diluted three times, and their diffusion was performed at 5°C. Synthesized polymers 2–4 were studied by chemical and X-ray diffraction analyses and IR spectroscopy.

AB - The slow diffusion of a γ,γ′-dipyridyl adduct solution in methanol into a methanol solution of the adduct M[(OOCPh]2[O(H)Me]4 (1) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh)2[O(H)Me]2}n (M = Ni (2), green; Co (3), orange) and {(dipy)2Co2(µ-OOCPh)2(η2-OOCPh)2 ⋅ MeOH}n (4), pink). Orange polymer 3 was the only product when the initial reagents were diluted three times, and their diffusion was performed at 5°C. Synthesized polymers 2–4 were studied by chemical and X-ray diffraction analyses and IR spectroscopy.

KW - N-donor

KW - nickel and cobalt benzoates

KW - synthesis

KW - X-ray diffraction analysis

KW - METHANOL

KW - METAL-ORGANIC FRAMEWORKS

KW - COPPER(II)

KW - COMPLEXES

KW - ZN(II)

KW - CO(II)

KW - ADDUCT

KW - NI(II)

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U2 - 10.1134/S0036023619100036

DO - 10.1134/S0036023619100036

M3 - Article

AN - SCOPUS:85074763302

VL - 64

SP - 1220

EP - 1228

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 10

ER -