TY - JOUR
T1 - Coordination polymers based on rhenium octahedral chalcocyanide cluster [Re6Se8(CN)6]4– and lanthanide ions solvated with dimethylformamide
AU - Litvinova, Yulia M.
AU - Gayfulin, Yakov M.
AU - Samsonenko, Denis G.
AU - Dorovatovskiy, Pavel V.
AU - Lazarenko, Vladimir A.
AU - Brylev, Konstantin A.
AU - Mironov, Yuri V.
N1 - Funding Information:
This work is supported by the Russian Foundation for Basic Research (project 18-29-04007). Luminescence measurements were supported by the grant of Russian Science Foundation (project 19-73-20196). Measurements were performed in ?Center for Optical and Laser materials research? (St. Petersburg State University, St. Petersburg, Russian Federation). The research was supported by the Ministry of Science and Higher Education of the Russian Federation, N 121031700321-3. Authors are grateful to V.Y. Komarov, PhD and T.S. Sukhikh, PhD for data collection performed in XRD Facility of NIIC SB RAS.
Funding Information:
This work is supported by the Russian Foundation for Basic Research (project 18-29-04007). Luminescence measurements were supported by the grant of Russian Science Foundation (project 19-73-20196). Measurements were performed in “Center for Optical and Laser materials research” (St. Petersburg State University, St. Petersburg, Russian Federation). The research was supported by the Ministry of Science and Higher Education of the Russian Federation, N 121031700321-3. Authors are grateful to V.Y. Komarov, PhD and T.S. Sukhikh, PhD for data collection performed in XRD Facility of NIIC SB RAS.
Publisher Copyright:
© 2021 Elsevier B.V.
PY - 2021/12/1
Y1 - 2021/12/1
N2 - In this work, we demonstrate influence of the source of organic ligand on the formation of supramolecular structures based on the octahedral metal clusters. Two series of coordination polymers based on the rhenium clusters [Re6Se8(CN)6]4– and Ln3+ complexes (Ln = Sm, Eu, Tb, Dy) with dimethylformamide (DMF) were obtained. The first series was obtained by direct addition of DMF in the reaction mixture. The series consist of the compounds crystallizing in trigonal crystal system, R3̅c space group, and possessing a framework porous structures composed of cluster anions and [Ln(dmf)3(H2O)2]3+ complexes. Compounds of the second series were obtained as a result of in situ generation of DMF by hydrolysis of N,N-dimethylformamide dimethyl acetal (DMF DMA). These compounds were crystallized in orthorhombic crystal system, Pnma space group, and possessed a layered structure consisting of cluster anions and [Ln(dmf)2(H2O)2]3+ complexes. It was found that the difference in the structures formed depends on the source of DMF rather than other reaction conditions.
AB - In this work, we demonstrate influence of the source of organic ligand on the formation of supramolecular structures based on the octahedral metal clusters. Two series of coordination polymers based on the rhenium clusters [Re6Se8(CN)6]4– and Ln3+ complexes (Ln = Sm, Eu, Tb, Dy) with dimethylformamide (DMF) were obtained. The first series was obtained by direct addition of DMF in the reaction mixture. The series consist of the compounds crystallizing in trigonal crystal system, R3̅c space group, and possessing a framework porous structures composed of cluster anions and [Ln(dmf)3(H2O)2]3+ complexes. Compounds of the second series were obtained as a result of in situ generation of DMF by hydrolysis of N,N-dimethylformamide dimethyl acetal (DMF DMA). These compounds were crystallized in orthorhombic crystal system, Pnma space group, and possessed a layered structure consisting of cluster anions and [Ln(dmf)2(H2O)2]3+ complexes. It was found that the difference in the structures formed depends on the source of DMF rather than other reaction conditions.
KW - Cluster
KW - Coordination polymer
KW - Crystal structure
KW - Cyanometallate
KW - Lanthanide
KW - Rhenium
UR - http://www.scopus.com/inward/record.url?scp=85114331542&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2021.120597
DO - 10.1016/j.ica.2021.120597
M3 - Article
AN - SCOPUS:85114331542
VL - 528
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
M1 - 120597
ER -