Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties

T. E. Kokina; O. V. Salomatina; I. I. Popadyuk; L. A. Glinskaya; I. V. Korol’kov; L. A. Sheludyakova; M. I. Rakhmanova; N. F. Salakhutdinov

doi:10.1134/S1070328419070030

Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties

T. E. Kokina, O. V. Salomatina, I. I. Popadyuk, L. A. Glinskaya, I. V. Korol’kov, L. A. Sheludyakova, M. I. Rakhmanova, N. F. Salakhutdinov

Research output: Contribution to journal › Article › peer-review

Abstract

Abstract: Complexes [Zn(L)Cl₂] (I), Cu(L)Cl₂ ∙ H₂O (II), Zn(L¹)Cl₂ ∙ 0.5H₂O (III), and Cu(L¹)Cl₂ ∙ 0.5H₂O (IV) (where L and L¹ are the diaminopropylene and diaminoethylene derivatives of deoxycholic acid, respectively) are synthesized. The structure of mononuclear complex I is determined by X-ray structure analysis (CIF file CCDC no. 1875305). The coordination polyhedron of the Zn atom (Cl₂N₂) is a distorted tetrahedron. According to the X-ray diffraction data, the crystals of compounds III and IV are isostructural. It is shown by IR spectroscopy that the structures of complexes II–IV are similar to that of complex I. In the solid phase, compounds L and L¹ possess photoluminescence in the visible spectral range (λ_max = 440 and 415 nm, respectively). Complex formation with Zn²⁺ ions does not change the photoluminescence properties of L and L¹.

Original language	English
Pages (from-to)	505-511
Number of pages	7
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	45
Issue number	7
DOIs	https://doi.org/10.1134/S1070328419070030
Publication status	Published - 1 Jul 2019

Keywords

complexes
copper
crystal structure
deoxycholic acid
synthesis
zinc
LIGANDS
SPECTROSCOPIC PROPERTIES
CRYSTAL
BILE-ACIDS

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Kokina, T. E., Salomatina, O. V., Popadyuk, I. I., Glinskaya, L. A., Korol’kov, I. V., Sheludyakova, L. A., Rakhmanova, M. I., & Salakhutdinov, N. F. (2019). Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 45(7), 505-511. https://doi.org/10.1134/S1070328419070030

@article{b37ecc425dcd4f668ec1e9854e870003,

title = "Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties",

abstract = "Abstract: Complexes [Zn(L)Cl2] (I), Cu(L)Cl2 ∙ H2O (II), Zn(L1)Cl2 ∙ 0.5H2O (III), and Cu(L1)Cl2 ∙ 0.5H2O (IV) (where L and L1 are the diaminopropylene and diaminoethylene derivatives of deoxycholic acid, respectively) are synthesized. The structure of mononuclear complex I is determined by X-ray structure analysis (CIF file CCDC no. 1875305). The coordination polyhedron of the Zn atom (Cl2N2) is a distorted tetrahedron. According to the X-ray diffraction data, the crystals of compounds III and IV are isostructural. It is shown by IR spectroscopy that the structures of complexes II–IV are similar to that of complex I. In the solid phase, compounds L and L1 possess photoluminescence in the visible spectral range (λmax = 440 and 415 nm, respectively). Complex formation with Zn2+ ions does not change the photoluminescence properties of L and L1.",

keywords = "complexes, copper, crystal structure, deoxycholic acid, synthesis, zinc, LIGANDS, SPECTROSCOPIC PROPERTIES, CRYSTAL, BILE-ACIDS",

author = "Kokina, {T. E.} and Salomatina, {O. V.} and Popadyuk, {I. I.} and Glinskaya, {L. A.} and Korol{\textquoteright}kov, {I. V.} and Sheludyakova, {L. A.} and Rakhmanova, {M. I.} and Salakhutdinov, {N. F.}",

note = "Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Ltd.",

year = "2019",

month = jul,

day = "1",

doi = "10.1134/S1070328419070030",

language = "English",

volume = "45",

pages = "505--511",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "7",

}

Kokina, TE, Salomatina, OV, Popadyuk, II, Glinskaya, LA, Korol’kov, IV, Sheludyakova, LA, Rakhmanova, MI & Salakhutdinov, NF 2019, 'Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 7, pp. 505-511. https://doi.org/10.1134/S1070328419070030

TY - JOUR

T1 - Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid

T2 - Syntheses, Structures, and Properties

AU - Kokina, T. E.

AU - Salomatina, O. V.

AU - Popadyuk, I. I.

AU - Glinskaya, L. A.

AU - Korol’kov, I. V.

AU - Sheludyakova, L. A.

AU - Rakhmanova, M. I.

AU - Salakhutdinov, N. F.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Abstract: Complexes [Zn(L)Cl2] (I), Cu(L)Cl2 ∙ H2O (II), Zn(L1)Cl2 ∙ 0.5H2O (III), and Cu(L1)Cl2 ∙ 0.5H2O (IV) (where L and L1 are the diaminopropylene and diaminoethylene derivatives of deoxycholic acid, respectively) are synthesized. The structure of mononuclear complex I is determined by X-ray structure analysis (CIF file CCDC no. 1875305). The coordination polyhedron of the Zn atom (Cl2N2) is a distorted tetrahedron. According to the X-ray diffraction data, the crystals of compounds III and IV are isostructural. It is shown by IR spectroscopy that the structures of complexes II–IV are similar to that of complex I. In the solid phase, compounds L and L1 possess photoluminescence in the visible spectral range (λmax = 440 and 415 nm, respectively). Complex formation with Zn2+ ions does not change the photoluminescence properties of L and L1.

AB - Abstract: Complexes [Zn(L)Cl2] (I), Cu(L)Cl2 ∙ H2O (II), Zn(L1)Cl2 ∙ 0.5H2O (III), and Cu(L1)Cl2 ∙ 0.5H2O (IV) (where L and L1 are the diaminopropylene and diaminoethylene derivatives of deoxycholic acid, respectively) are synthesized. The structure of mononuclear complex I is determined by X-ray structure analysis (CIF file CCDC no. 1875305). The coordination polyhedron of the Zn atom (Cl2N2) is a distorted tetrahedron. According to the X-ray diffraction data, the crystals of compounds III and IV are isostructural. It is shown by IR spectroscopy that the structures of complexes II–IV are similar to that of complex I. In the solid phase, compounds L and L1 possess photoluminescence in the visible spectral range (λmax = 440 and 415 nm, respectively). Complex formation with Zn2+ ions does not change the photoluminescence properties of L and L1.

KW - complexes

KW - copper

KW - crystal structure

KW - deoxycholic acid

KW - synthesis

KW - zinc

KW - LIGANDS

KW - SPECTROSCOPIC PROPERTIES

KW - CRYSTAL

KW - BILE-ACIDS

UR - http://www.scopus.com/inward/record.url?scp=85068783617&partnerID=8YFLogxK

U2 - 10.1134/S1070328419070030

DO - 10.1134/S1070328419070030

M3 - Article

AN - SCOPUS:85068783617

VL - 45

SP - 505

EP - 511

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 7

ER -

Complexes of Zn(II) and Сu(II) with the Amino Derivatives of Deoxycholic Acid: Syntheses, Structures, and Properties

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