Cobalt(II) hexaiododimercurate(II) complex with ε-caprolactam: Synthesis and crystal structure

A. V. Tikhomirova, I. Yu Bagryanskaya, N. V. Pervukhina, T. G. Cherkasova

Research output: Contribution to journalArticlepeer-review

Abstract

The conditions of synthesis of a new binary complex salt [Co(Cpl)6][Hg2I6] (Cpl is ε-caprolactam ε-C6H11NO) have been developed, and its structure has been characterized. The salt crystallizes in triclinic system, space group P1 ¯ , a = 10.1078(4) Å, b = 12.2680(5) Å, c = 13.0782(5) Å, α = 62.872(2)°, β = 72.394(2)°, γ = 76.834(2)°, V = 1367.98(9) Å3, Z = 1, and ρcalc = 2.297 g/cm3. The structure is insular and consists of isolated ions.

Original languageEnglish
Pages (from-to)187-190
Number of pages4
JournalRussian Journal of Inorganic Chemistry
Volume62
Issue number2
DOIs
Publication statusPublished - 1 Feb 2017

Keywords

  • ANIONS

Fingerprint Dive into the research topics of 'Cobalt(II) hexaiododimercurate(II) complex with ε-caprolactam: Synthesis and crystal structure'. Together they form a unique fingerprint.

Cite this