Chlorobismuthates Trapping Dibromine: Formation of Two-Dimensional Supramolecular Polyhalide Networks with Br2 Linkers

Sergey A. Adonin, Igor D. Gorokh, Pavel A. Abramov, Alexander S. Novikov, Ilya V. Korolkov, Maxim N. Sokolov, Vladimir P. Fedin

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

Reactions between BiCl3, Br2, and chlorides of pyridinium (1), 4,4′-propylenedipyridinium (2), or trimethylphenylammonium (3) in aqueous HCl lead to the formation of chlorobismuthate complexes trapping {Br2} in the solid state into two-dimensional polyhalide supramolecular networks. The nature of non-covalent Br···Cl interactions was studied by theoretical methods; estimated energies of these interactions are 1.9–6.0 kcal/mol.

Original languageEnglish
Pages (from-to)4925-4929
Number of pages5
JournalEuropean Journal of Inorganic Chemistry
Volume2017
Issue number42
DOIs
Publication statusPublished - 16 Nov 2017

Keywords

  • Density functional calculations
  • Halogens
  • Halometalates
  • Polyhalides
  • QTAIM

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