Chiral guest in a chiral framework: X-ray diffraction study

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6 Citations (Scopus)

Abstract

The inclusion compound of zinc lactate terephthalate with R-butan-2-ol, [Zn2(R-BusOH) (bdc)(S-lac)]•(R-BusOH) (BusOH is butan-2-ol, H2bdc is terephthalic acid, S-H2lac is lactic acid), was prepared by soaking crystals of [Zn2(dmf)(bdc)(S-lac)]•DMF in pure R-butan-2-ol. The positions of chiral alcohol molecules in voids of the chiral framework and the host–guest contacts were determined by X-ray diffraction. These data provide an explanation for the origin of chiral discrimination of zinc lactate terephthalate toward the R-isomer of butan-2-ol.

Original languageEnglish
Pages (from-to)1268-1272
Number of pages5
JournalRussian Chemical Bulletin
Volume67
Issue number7
DOIs
Publication statusPublished - 1 Jul 2018

Keywords

  • chiral alcohols
  • coordination polymers
  • crystal structure
  • inclusion compounds
  • lactic acid
  • zinc complexes
  • CRYSTAL-STRUCTURE
  • MEMBRANE
  • ADSORPTION
  • INCLUSION COMPOUND
  • ALCOHOLS
  • METAL-ORGANIC FRAMEWORKS
  • POLYMER
  • ENANTIOSELECTIVE SORPTION
  • SEPARATION

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