Abstract
The inclusion compound of zinc lactate terephthalate with R-butan-2-ol, [Zn2(R-BusOH) (bdc)(S-lac)]•(R-BusOH) (BusOH is butan-2-ol, H2bdc is terephthalic acid, S-H2lac is lactic acid), was prepared by soaking crystals of [Zn2(dmf)(bdc)(S-lac)]•DMF in pure R-butan-2-ol. The positions of chiral alcohol molecules in voids of the chiral framework and the host–guest contacts were determined by X-ray diffraction. These data provide an explanation for the origin of chiral discrimination of zinc lactate terephthalate toward the R-isomer of butan-2-ol.
Original language | English |
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Pages (from-to) | 1268-1272 |
Number of pages | 5 |
Journal | Russian Chemical Bulletin |
Volume | 67 |
Issue number | 7 |
DOIs | |
Publication status | Published - 1 Jul 2018 |
Keywords
- chiral alcohols
- coordination polymers
- crystal structure
- inclusion compounds
- lactic acid
- zinc complexes
- CRYSTAL-STRUCTURE
- MEMBRANE
- ADSORPTION
- INCLUSION COMPOUND
- ALCOHOLS
- METAL-ORGANIC FRAMEWORKS
- POLYMER
- ENANTIOSELECTIVE SORPTION
- SEPARATION