Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines

D. S. Suslov; M. V. Bykov; M. V. Pakhomova; P. A. Abramov; I. A. Ushakov; V. S. Tkach

doi:10.1016/j.catcom.2017.02.004

Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines

D. S. Suslov, M. V. Bykov, M. V. Pakhomova, P. A. Abramov, I. A. Ushakov, V. S. Tkach

Laboratory for Functional Materials on the Basis of Clusters and Supramolecular Compounds

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A simple and solvent-free protocol using cationic acetylacetonate palladium complexes with mono-/bidentate phosphine ligands activated with BF₃·OEt₂as in situ-formed catalyst for hydroamination of vinylarenes with arylamines have been developed. Excellent catalytic activities were obtained using [Pd(acac)(PPh₃)₂][BF₄]/BF₃·OEt₂/i-PrOH catalyst system with the addition of a small amount of palladium (0.2–0.05 mol%) to the reaction mixture. Furthermore, the novel unexpected diphosphine-bridged palladium complexes have been prepared and characterized: [Pd(acac)(dpppt)]₂[BF₄]₂and [Pd(acac)(dpph)]₂[BF₄]₂(dpppt – 1,5-bis(diphenylphosphino)pentane, dpph – 1,6-bis(diphenylphosphino)hexane)

Original language	English
Pages (from-to)	69-72
Number of pages	4
Journal	Catalysis Communications
Volume	94
DOIs	https://doi.org/10.1016/j.catcom.2017.02.004
Publication status	Published - 5 May 2017

Keywords

Acetylacetonate
Aniline
Hydroamination
Palladium
Styrene
AMINATION
PHOSPHINE
METAL

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10.1016/j.catcom.2017.02.004

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@article{961b280697d64409999b45028069e31d,

title = "Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines",

abstract = "A simple and solvent-free protocol using cationic acetylacetonate palladium complexes with mono-/bidentate phosphine ligands activated with BF3·OEt2as in situ-formed catalyst for hydroamination of vinylarenes with arylamines have been developed. Excellent catalytic activities were obtained using [Pd(acac)(PPh3)2][BF4]/BF3·OEt2/i-PrOH catalyst system with the addition of a small amount of palladium (0.2–0.05 mol%) to the reaction mixture. Furthermore, the novel unexpected diphosphine-bridged palladium complexes have been prepared and characterized: [Pd(acac)(dpppt)]2[BF4]2and [Pd(acac)(dpph)]2[BF4]2(dpppt – 1,5-bis(diphenylphosphino)pentane, dpph – 1,6-bis(diphenylphosphino)hexane)",

keywords = "Acetylacetonate, Aniline, Hydroamination, Palladium, Styrene, AMINATION, PHOSPHINE, METAL",

author = "Suslov, {D. S.} and Bykov, {M. V.} and Pakhomova, {M. V.} and Abramov, {P. A.} and Ushakov, {I. A.} and Tkach, {V. S.}",

year = "2017",

month = may,

day = "5",

doi = "10.1016/j.catcom.2017.02.004",

language = "English",

volume = "94",

pages = "69--72",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier",

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TY - JOUR

T1 - Cationic acetylacetonate palladium complexes/boron trifluoride etherate catalyst systems for hydroamination of vinylarenes using arylamines

AU - Suslov, D. S.

AU - Bykov, M. V.

AU - Pakhomova, M. V.

AU - Abramov, P. A.

AU - Ushakov, I. A.

AU - Tkach, V. S.

PY - 2017/5/5

Y1 - 2017/5/5

N2 - A simple and solvent-free protocol using cationic acetylacetonate palladium complexes with mono-/bidentate phosphine ligands activated with BF3·OEt2as in situ-formed catalyst for hydroamination of vinylarenes with arylamines have been developed. Excellent catalytic activities were obtained using [Pd(acac)(PPh3)2][BF4]/BF3·OEt2/i-PrOH catalyst system with the addition of a small amount of palladium (0.2–0.05 mol%) to the reaction mixture. Furthermore, the novel unexpected diphosphine-bridged palladium complexes have been prepared and characterized: [Pd(acac)(dpppt)]2[BF4]2and [Pd(acac)(dpph)]2[BF4]2(dpppt – 1,5-bis(diphenylphosphino)pentane, dpph – 1,6-bis(diphenylphosphino)hexane)

AB - A simple and solvent-free protocol using cationic acetylacetonate palladium complexes with mono-/bidentate phosphine ligands activated with BF3·OEt2as in situ-formed catalyst for hydroamination of vinylarenes with arylamines have been developed. Excellent catalytic activities were obtained using [Pd(acac)(PPh3)2][BF4]/BF3·OEt2/i-PrOH catalyst system with the addition of a small amount of palladium (0.2–0.05 mol%) to the reaction mixture. Furthermore, the novel unexpected diphosphine-bridged palladium complexes have been prepared and characterized: [Pd(acac)(dpppt)]2[BF4]2and [Pd(acac)(dpph)]2[BF4]2(dpppt – 1,5-bis(diphenylphosphino)pentane, dpph – 1,6-bis(diphenylphosphino)hexane)

KW - Acetylacetonate

KW - Aniline

KW - Hydroamination

KW - Palladium

KW - Styrene

KW - AMINATION

KW - PHOSPHINE

KW - METAL

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U2 - 10.1016/j.catcom.2017.02.004

DO - 10.1016/j.catcom.2017.02.004

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EP - 72

JO - Catalysis Communications

JF - Catalysis Communications

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