TY - JOUR
T1 - Calibration of the goniometer equatorial circumference and the refinement of unit cell parameters of [Pt(NH3)4]MO4 (М = Cr, Mo, W)
AU - Serebrennikova, P. S.
AU - Gromilov, S. A.
N1 - Funding Information:
The work was supported by the Ministry of Science and Higher Education (project No. 121031700313-8) and Priority 2030.
Funding Information:
The authors are thankful to V. I. Lagunova for kindly provided samples of [Pt(NH)]MO (М = Cr, Mo, W). (The work was supported by Russian Science Foundation grant No. 22-23-00672). 3 4 4
Publisher Copyright:
© 2022, Pleiades Publishing, Ltd.
PY - 2022/11
Y1 - 2022/11
N2 - A calibration procedure for the three-circle goniometer/2D detector system is described. It is based on the construction of calibration graphs Δ2θ(2θ) from the results of processing Kα1 and Kα2 components of external reference reflections successively brought to the equatorial circumference. A Si single crystal is used as the reference. Random errors are estimated. Results of the refinement of unit cell parameters of [Pt(NH3)4]MO4 (М = Cr, Mo, W) are compared by several procedures, including the obtained calibration. The relative error of the performed measurements does not exceed 2·10–4.
AB - A calibration procedure for the three-circle goniometer/2D detector system is described. It is based on the construction of calibration graphs Δ2θ(2θ) from the results of processing Kα1 and Kα2 components of external reference reflections successively brought to the equatorial circumference. A Si single crystal is used as the reference. Random errors are estimated. Results of the refinement of unit cell parameters of [Pt(NH3)4]MO4 (М = Cr, Mo, W) are compared by several procedures, including the obtained calibration. The relative error of the performed measurements does not exceed 2·10–4.
KW - accuracy
KW - single crystal X-ray diffraction
KW - unit cell parameters
UR - http://www.scopus.com/inward/record.url?scp=85143535658&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/25fe686c-cd91-3b62-9b68-95ad158921cc/
U2 - 10.1134/S0022476622110129
DO - 10.1134/S0022476622110129
M3 - Article
AN - SCOPUS:85143535658
VL - 63
SP - 1820
EP - 1830
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 11
ER -