Bromo- and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen-Rich Halometalate Frameworks

Sergey A. Adonin, Mikhail A. Bondarenko, Pavel A. Abramov, Alexander S. Novikov, Pavel E. Plyusnin, Maxim N. Sokolov, Vladimir P. Fedin

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

Cation-dependent reactions “[SbBr6]3−+Br2+HBr+CationBrx” result in the formation of bromide/polybromide complexes with zero-, one-, two-, or three-dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol−1).

Original languageEnglish
Pages (from-to)10165-10170
Number of pages6
JournalChemistry - A European Journal
Volume24
Issue number40
Early online date23 Apr 2018
DOIs
Publication statusPublished - 17 Jul 2018

Keywords

  • antimony
  • DFT calculations
  • halide complexes
  • non-covalent interactions
  • polyhalide

Fingerprint

Dive into the research topics of 'Bromo- and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen-Rich Halometalate Frameworks'. Together they form a unique fingerprint.

Cite this