Abstract

Three novel polybromide complexes of bismuth(iii)-(2,6-MePyH)3[BiBr5(Br3)] (1), (H2bpp){[BiBr5](Br2)} (2) and (3-ClPyH)2{[BiBr5](Br2)} (3)-were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(iii) polybromides are presented and discussed. The nature of Br⋯Br interactions in Bi(iii) polybromides was investigated by theoretical methods, enabling the estimation of their energies.

Original languageEnglish
Pages (from-to)2683-2689
Number of pages7
JournalDalton Transactions
Volume47
Issue number8
DOIs
Publication statusPublished - 28 Feb 2018

Keywords

  • TEMPERATURE IONIC LIQUID
  • ZETA BASIS-SETS
  • CRYSTAL-STRUCTURE
  • PHENYLTRIMETHYLAMMONIUM SALTS
  • NONCOVALENT INTERACTIONS
  • CENTER-DOT
  • HALOGEN
  • NETWORKS
  • NONABROMOANTIMONATE(V)
  • POLYBROMIDES

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