Azo dyes containing 1,3,4-thiadiazole fragment: Synthesis and properties

Galina Selivanova, Alexandrina Skolyapova, Jiaying Wang, Elena Karpova, Inna Shundrina, Irina Bagryanskaya, Evgeny Amosov

Research output: Contribution to journalArticlepeer-review

Abstract

New 1,3,4-thiadiazole derivatives containing a diazenyl group, as well as both a diazenyl and an imino group, were synthesized and their optical and thermal properties were investigated. Initially, new azo compounds containing an azo group directly in the thiadiazole block were obtained by the coupling of diazonium bisulfates based on the previously known 5-derivatives of 2-amino-1,3,4-thiadiazoles with N,N-dialkyl anilines (N(n-Bu)2, NEt2, and NEt(EtOH)). Schiff bases were obtained by the interaction of p-toluidine, p-phenylenediamine and p-aminophenol with azo compounds containing an aldehyde group in the 1,3,4-thiadiazole ring. The new dyes were characterized by spectral (IR, UV, 1H NMR, 13C NMR and mass spectra) and X-ray analyses. This journal is

Original languageEnglish
Pages (from-to)1929-1942
Number of pages14
JournalNew Journal of Chemistry
Volume46
Issue number4
DOIs
Publication statusPublished - 28 Jan 2022

OECD FOS+WOS

  • 2.05 MATERIALS ENGINEERING
  • 2.04 CHEMICAL ENGINEERING
  • 1.04 CHEMICAL SCIENCES

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