Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole

Dmitry I. Konovalov; Anton A. Ivanov; Yuri A. Vorotnikov; Konstantin A. Brylev; Ilia V. Eltsov; Vadim V. Yanshole; Natalia V. Kuratieva; Noboru Kitamura; Michael A. Shestopalov

doi:10.1016/j.ica.2020.119738

Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole

Dmitry I. Konovalov, Anton A. Ivanov, Yuri A. Vorotnikov, Konstantin A. Brylev, Ilia V. Eltsov, Vadim V. Yanshole, Natalia V. Kuratieva, Noboru Kitamura, Michael A. Shestopalov

Research output: Contribution to journal › Article › peer-review

Abstract

Octahedral rhenium cluster complexes with organic apical ligands have a high potential to be used in different fields due to their intrinsic luminescence and X-ray contrast properties. A series of new compounds based on cations [{Re₆Q₈}(3-Me-pzH)₆]²⁺, where Q is S or Se and 3-Me-pzH is 3-methylpyrazole, were obtained and characterized in the solid state (FTIR, elemental and single crystal diffraction analysis) and in solution (¹H NMR and ESI-MS). The compounds possess luminescence properties that mainly depend on inner Q ligands indicating the {Re₆Q₈}²⁺ core-centered nature of emission.

Original language	English
Article number	119738
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	510
DOIs	https://doi.org/10.1016/j.ica.2020.119738
Publication status	Published - 24 Sep 2020

Keywords

3-methylpyrazole
Crystal structure
Luminescence
Rhenium cluster
SUPRAMOLECULAR ARRAYS
Q=S
HEXARHENIUM(III) CLUSTERS
SE
LUMINESCENCE
LIGANDS
SOLIDS
REDOX
METAL
EMISSION

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@article{5cd3913e582145c391b48478b7e4f7df,

title = "Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole",

abstract = "Octahedral rhenium cluster complexes with organic apical ligands have a high potential to be used in different fields due to their intrinsic luminescence and X-ray contrast properties. A series of new compounds based on cations [{Re6Q8}(3-Me-pzH)6]2+, where Q is S or Se and 3-Me-pzH is 3-methylpyrazole, were obtained and characterized in the solid state (FTIR, elemental and single crystal diffraction analysis) and in solution (1H NMR and ESI-MS). The compounds possess luminescence properties that mainly depend on inner Q ligands indicating the {Re6Q8}2+ core-centered nature of emission.",

keywords = "3-methylpyrazole, Crystal structure, Luminescence, Rhenium cluster, SUPRAMOLECULAR ARRAYS, Q=S, HEXARHENIUM(III) CLUSTERS, SE, LUMINESCENCE, LIGANDS, SOLIDS, REDOX, METAL, EMISSION",

author = "Konovalov, {Dmitry I.} and Ivanov, {Anton A.} and Vorotnikov, {Yuri A.} and Brylev, {Konstantin A.} and Eltsov, {Ilia V.} and Yanshole, {Vadim V.} and Kuratieva, {Natalia V.} and Noboru Kitamura and Shestopalov, {Michael A.}",

year = "2020",

month = sep,

day = "24",

doi = "10.1016/j.ica.2020.119738",

language = "English",

volume = "510",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole. / Konovalov, Dmitry I.; Ivanov, Anton A.; Vorotnikov, Yuri A.; Brylev, Konstantin A.; Eltsov, Ilia V.; Yanshole, Vadim V.; Kuratieva, Natalia V.; Kitamura, Noboru; Shestopalov, Michael A.

In: Inorganica Chimica Acta, Vol. 510, 119738, 24.09.2020.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole

AU - Konovalov, Dmitry I.

AU - Ivanov, Anton A.

AU - Vorotnikov, Yuri A.

AU - Brylev, Konstantin A.

AU - Eltsov, Ilia V.

AU - Yanshole, Vadim V.

AU - Kuratieva, Natalia V.

AU - Kitamura, Noboru

AU - Shestopalov, Michael A.

PY - 2020/9/24

Y1 - 2020/9/24

N2 - Octahedral rhenium cluster complexes with organic apical ligands have a high potential to be used in different fields due to their intrinsic luminescence and X-ray contrast properties. A series of new compounds based on cations [{Re6Q8}(3-Me-pzH)6]2+, where Q is S or Se and 3-Me-pzH is 3-methylpyrazole, were obtained and characterized in the solid state (FTIR, elemental and single crystal diffraction analysis) and in solution (1H NMR and ESI-MS). The compounds possess luminescence properties that mainly depend on inner Q ligands indicating the {Re6Q8}2+ core-centered nature of emission.

AB - Octahedral rhenium cluster complexes with organic apical ligands have a high potential to be used in different fields due to their intrinsic luminescence and X-ray contrast properties. A series of new compounds based on cations [{Re6Q8}(3-Me-pzH)6]2+, where Q is S or Se and 3-Me-pzH is 3-methylpyrazole, were obtained and characterized in the solid state (FTIR, elemental and single crystal diffraction analysis) and in solution (1H NMR and ESI-MS). The compounds possess luminescence properties that mainly depend on inner Q ligands indicating the {Re6Q8}2+ core-centered nature of emission.

KW - 3-methylpyrazole

KW - Crystal structure

KW - Luminescence

KW - Rhenium cluster

KW - SUPRAMOLECULAR ARRAYS

KW - Q=S

KW - HEXARHENIUM(III) CLUSTERS

KW - SE

KW - LUMINESCENCE

KW - LIGANDS

KW - SOLIDS

KW - REDOX

KW - METAL

KW - EMISSION

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DO - 10.1016/j.ica.2020.119738

M3 - Article

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VL - 510

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

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