Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens

Sofya Artemkina; Anastasiia Poltarak; Pavel Poltarak; Ekaterina Grayfer; Denis Samsonenko; Vladimir Fedorov

doi:10.1016/j.ica.2020.119875

Amorphous pentasulfides MS₅ (M = Mo, W) in reactions with thiuram disulfide and halogens

Sofya Artemkina, Anastasiia Poltarak, Pavel Poltarak, Ekaterina Grayfer, Denis Samsonenko, Vladimir Fedorov

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Amorphous pentasulfides MoS₅ and WS₅ were studied in a series of chemical reactions for the first time. Interaction of MoS₅ and WS₅ with melt of tetramethylthiuramdisulfide resulted in two new molecular complexes, [{Mo₃S₇}(dtc)₃](S₃H) and [{W₃S₄}(dtc)₄(Me₂NCHS)]. Halogenation of MoS₅ and WS₅ resulted in cluster coordination polymers M₃S₇Hal₄ (M = Mo, W; Hal = Cl, Br).

Original language	English
Article number	119875
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	512
DOIs	https://doi.org/10.1016/j.ica.2020.119875
Publication status	Published - 1 Nov 2020

Keywords

Amorphous metal polysulfides
Crystal structure
Dithiocarbamate ligand
Molybdenum pentasulfide
Triangular cluster complex
Tungsten pentasulfide
CONVERSION
CRYSTAL-STRUCTURE
SULFUR-DIOXIDE
COMPLEXES
ZIRCONIUM TRISULFIDE
STRUCTURAL-CHARACTERIZATION
POSITIVE-ELECTRODE
X-RAY PHOTOELECTRON
CLUSTER
ELECTRONIC-STRUCTURE

OECD FOS+WOS

1.04 CHEMICAL SCIENCES

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10.1016/j.ica.2020.119875

Cite this

@article{d98a6b8760e04bdf8820136b7d1afbfe,

title = "Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens",

abstract = "Amorphous pentasulfides MoS5 and WS5 were studied in a series of chemical reactions for the first time. Interaction of MoS5 and WS5 with melt of tetramethylthiuramdisulfide resulted in two new molecular complexes, [{Mo3S7}(dtc)3](S3H) and [{W3S4}(dtc)4(Me2NCHS)]. Halogenation of MoS5 and WS5 resulted in cluster coordination polymers M3S7Hal4 (M = Mo, W; Hal = Cl, Br).",

keywords = "Amorphous metal polysulfides, Crystal structure, Dithiocarbamate ligand, Molybdenum pentasulfide, Triangular cluster complex, Tungsten pentasulfide, CONVERSION, CRYSTAL-STRUCTURE, SULFUR-DIOXIDE, COMPLEXES, ZIRCONIUM TRISULFIDE, STRUCTURAL-CHARACTERIZATION, POSITIVE-ELECTRODE, X-RAY PHOTOELECTRON, CLUSTER, ELECTRONIC-STRUCTURE",

author = "Sofya Artemkina and Anastasiia Poltarak and Pavel Poltarak and Ekaterina Grayfer and Denis Samsonenko and Vladimir Fedorov",

year = "2020",

month = nov,

day = "1",

doi = "10.1016/j.ica.2020.119875",

language = "English",

volume = "512",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

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TY - JOUR

T1 - Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens

AU - Artemkina, Sofya

AU - Poltarak, Anastasiia

AU - Poltarak, Pavel

AU - Grayfer, Ekaterina

AU - Samsonenko, Denis

AU - Fedorov, Vladimir

PY - 2020/11/1

Y1 - 2020/11/1

N2 - Amorphous pentasulfides MoS5 and WS5 were studied in a series of chemical reactions for the first time. Interaction of MoS5 and WS5 with melt of tetramethylthiuramdisulfide resulted in two new molecular complexes, [{Mo3S7}(dtc)3](S3H) and [{W3S4}(dtc)4(Me2NCHS)]. Halogenation of MoS5 and WS5 resulted in cluster coordination polymers M3S7Hal4 (M = Mo, W; Hal = Cl, Br).

AB - Amorphous pentasulfides MoS5 and WS5 were studied in a series of chemical reactions for the first time. Interaction of MoS5 and WS5 with melt of tetramethylthiuramdisulfide resulted in two new molecular complexes, [{Mo3S7}(dtc)3](S3H) and [{W3S4}(dtc)4(Me2NCHS)]. Halogenation of MoS5 and WS5 resulted in cluster coordination polymers M3S7Hal4 (M = Mo, W; Hal = Cl, Br).

KW - Amorphous metal polysulfides

KW - Crystal structure

KW - Dithiocarbamate ligand

KW - Molybdenum pentasulfide

KW - Triangular cluster complex

KW - Tungsten pentasulfide

KW - CONVERSION

KW - CRYSTAL-STRUCTURE

KW - SULFUR-DIOXIDE

KW - COMPLEXES

KW - ZIRCONIUM TRISULFIDE

KW - STRUCTURAL-CHARACTERIZATION

KW - POSITIVE-ELECTRODE

KW - X-RAY PHOTOELECTRON

KW - CLUSTER

KW - ELECTRONIC-STRUCTURE

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U2 - 10.1016/j.ica.2020.119875

DO - 10.1016/j.ica.2020.119875

M3 - Article

AN - SCOPUS:85088378834

VL - 512

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 119875

ER -