Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens

Sofya Artemkina, Anastasiia Poltarak, Pavel Poltarak, Ekaterina Grayfer, Denis Samsonenko, Vladimir Fedorov

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Amorphous pentasulfides MoS5 and WS5 were studied in a series of chemical reactions for the first time. Interaction of MoS5 and WS5 with melt of tetramethylthiuramdisulfide resulted in two new molecular complexes, [{Mo3S7}(dtc)3](S3H) and [{W3S4}(dtc)4(Me2NCHS)]. Halogenation of MoS5 and WS5 resulted in cluster coordination polymers M3S7Hal4 (M = Mo, W; Hal = Cl, Br).

Original languageEnglish
Article number119875
Number of pages7
JournalInorganica Chimica Acta
Volume512
DOIs
Publication statusPublished - 1 Nov 2020

Keywords

  • Amorphous metal polysulfides
  • Crystal structure
  • Dithiocarbamate ligand
  • Molybdenum pentasulfide
  • Triangular cluster complex
  • Tungsten pentasulfide
  • CONVERSION
  • CRYSTAL-STRUCTURE
  • SULFUR-DIOXIDE
  • COMPLEXES
  • ZIRCONIUM TRISULFIDE
  • STRUCTURAL-CHARACTERIZATION
  • POSITIVE-ELECTRODE
  • X-RAY PHOTOELECTRON
  • CLUSTER
  • ELECTRONIC-STRUCTURE

OECD FOS+WOS

  • 1.04 CHEMICAL SCIENCES

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